4-(2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranosyloxymethyl)-1-(octyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-mannopyranoside-6-yl)-1H-1,2,3-triazole

Base Information

Chemical Name:4-(2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranosyloxymethyl)-1-(octyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-mannopyranoside-6-yl)-1H-1,2,3-triazole
CAS No.:1264635-75-7
Molecular Formula:C₄₂H₅₉N₃O₁₉S
Molecular Weight:942.005
Hs Code.:

Synonyms:4-(2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranosyloxymethyl)-1-(octyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-mannopyranoside-6-yl)-1H-1,2,3-triazole

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Chemical Property of 4-(2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranosyloxymethyl)-1-(octyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-mannopyranoside-6-yl)-1H-1,2,3-triazole

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Technology Process of 4-(2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranosyloxymethyl)-1-(octyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-mannopyranoside-6-yl)-1H-1,2,3-triazole

There total 8 articles about 4-(2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranosyloxymethyl)-1-(octyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-mannopyranoside-6-yl)-1H-1,2,3-triazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 1264635-72-4
octyl 2,3,4-tri-O-acetyl-6-azido-6-deoxy-α-D-mannopyranoside

: 1141387-58-7
2-propynyl 2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranoside

: 1264635-75-7
4-(2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranosyloxymethyl)-1-(octyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-mannopyranoside-6-yl)-1H-1,2,3-triazole

Guidance literature:: With copper(II) sulfate; sodium L-ascorbate; In water; N,N-dimethyl-formamide; at 20 ℃; for 4h; regioselective reaction;
DOI:10.1021/bc100421g

Reference yield:

: C₂₁H₃₄O₈S

: 1264635-75-7
4-(2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranosyloxymethyl)-1-(octyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-mannopyranoside-6-yl)-1H-1,2,3-triazole

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine / 16 h / 20 °C / Cooling with ice

2: sodium azide / N,N-dimethyl-formamide / 40 h / 80 °C

3: copper(II) sulfate; sodium L-ascorbate / water; N,N-dimethyl-formamide / 4 h / 20 °C

With pyridine; sodium azide; copper(II) sulfate; sodium L-ascorbate; In water; N,N-dimethyl-formamide;
DOI:10.1021/bc100421g

Reference yield:

: 124650-29-9
octyl α-D-mannopyranoside

: 1264635-75-7
4-(2,3,4-tri-O-acetyl-6-O-tosyl-α-D-mannopyranosyloxymethyl)-1-(octyl 2,3,4-tri-O-acetyl-6-deoxy-α-D-mannopyranoside-6-yl)-1H-1,2,3-triazole

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine / dichloromethane / 16 h / 20 °C / Cooling with ice

2: pyridine / 16 h / 20 °C / Cooling with ice

3: sodium azide / N,N-dimethyl-formamide / 40 h / 80 °C

4: copper(II) sulfate; sodium L-ascorbate / water; N,N-dimethyl-formamide / 4 h / 20 °C

With pyridine; sodium azide; copper(II) sulfate; sodium L-ascorbate; In dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/bc100421g