<2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde

Base Information

Chemical Name:<2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde
CAS No.:127492-49-3
Molecular Formula:C₃₃H₅₄O₆Si
Molecular Weight:574.874
Hs Code.:

<2S-<2α,4α,5α,6α<E(1S*,3S*,4S*)>>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<<tris(1-methylethyl)silyl>oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde

Synonyms:<2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde

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Chemical Property of <2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde

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Technology Process of <2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde

There total 10 articles about <2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 127492-48-2
<2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-ethanol

: 127492-49-3
<2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde

Guidance literature:: With pyridine; Dess-Martin periodane; In dichloromethane; for 1.5h; Ambient temperature;
DOI:10.1021/jo00296a042

Reference yield:

: 127492-46-0
(1R,2R,4R)-2-Methoxy-4-{(E)-2-[(2S,4S,5R,6S)-2-(4-methoxy-phenyl)-5-methyl-6-vinyl-[1,3]dioxan-4-yl]-propenyl}-cyclohexanol

: 127492-49-3
<2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 2,6-lutidine, DMAP / CH₂Cl₂ / 2 h / 0 °C

2: 1) 9-BBN 2) 1N aq. NaOH, 30percent aq. H₂O₂ / 1) THF, 4h, 0 deg C 2) 12h, r.t.

3: 86 percent / Dess-Martin periodinane, pyridine / CH₂Cl₂ / 1.5 h / Ambient temperature

With pyridine; 2,6-dimethylpyridine; dmap; sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide; Dess-Martin periodane; In dichloromethane;
DOI:10.1021/jo00296a042

Reference yield:

: 127492-47-1
<2S-<2α,4α,5α,6α>>-<<4-<2-<6-ethenyl-2-(4-methoxyphenyl)-5-methyl-1,3-dioxan-4-yl>-1-propenyl>-2-methoxycyclohexyl>oxy>tris-(1-methylethyl)silane

: 127492-49-3
<2S-<2α,4α,5α,6α>>-2-(4-Methoxyphenyl)-6-<2-<3-methoxy-4-<oxy>cyclohexyl>-1-methylethenyl>-5-methyl-1,3-dioxane-4-acetaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1: 1) 9-BBN 2) 1N aq. NaOH, 30percent aq. H₂O₂ / 1) THF, 4h, 0 deg C 2) 12h, r.t.

2: 86 percent / Dess-Martin periodinane, pyridine / CH₂Cl₂ / 1.5 h / Ambient temperature

With pyridine; sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide; Dess-Martin periodane; In dichloromethane;
DOI:10.1021/jo00296a042