benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate

Base Information

Chemical Name:benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate
CAS No.:293752-54-2
Molecular Formula:C₃₅H₄₈O₉
Molecular Weight:612.761
Hs Code.:

Synonyms:benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate

Suppliers and Price of benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate

There total 4 articles about benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 187404-16-6
benzyl (R)-3-cyclohexyl-2-trifluoromethanesulfonyloxy-propionate

: 293752-52-0
(1R,2R)-2-hydroxy-cyclohexyl 6-O-benzyl-β-D-galactopyranoside

: 293752-54-2
benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate

Guidance literature:: (1R,2R)-2-hydroxy-cyclohexyl 6-O-benzyl-β-D-galactopyranoside; With di(n-butyl)tin oxide; In methanol; for 2.5h; Heating;

benzyl (R)-3-cyclohexyl-2-trifluoromethanesulfonyloxy-propionate; With cesium fluoride; In dichloromethane; for 3h;
DOI:10.1139/v00-081

Reference yield:

: 1072-86-2,1460-57-7,1792-81-0,54383-22-1,57794-08-8,931-17-9
(1R,2R)-trans-1,2-cyclohexanediol

: 293752-54-2
benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: 67 percent / 4A MS; DMTST / CH₂Cl₂ / 3 h / 20 °C

2.1: 94 percent / MeONa; MeOH / 3 h / 20 °C

3.1: dibutyltin oxide / methanol / 2.5 h / Heating

3.2: 76 percent / CsF / CH₂Cl₂ / 3 h

With methanol; sodium methylate; di(n-butyl)tin oxide; dimethyl-(methylthio)-sulphonium trifluoromethanesulphonate; In methanol; dichloromethane; 1.1: glycosylation / 2.1: debenzoylation / 3.1: Condensation;
DOI:10.1139/v00-081

Reference yield:

: ethyl 6-O-benzyl-2,3,4-tri-O-benzoyl-thio-β-D-galactopyranoside

: 293752-54-2
benzyl (2S) 3-cyclohexyl-2-{1-O-[(1R,2R) cyclohexyl]-6-O-benzyl-β-D-galactopyranos-3-yl}propanoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: 67 percent / 4A MS; DMTST / CH₂Cl₂ / 3 h / 20 °C

2.1: 94 percent / MeONa; MeOH / 3 h / 20 °C

3.1: dibutyltin oxide / methanol / 2.5 h / Heating

3.2: 76 percent / CsF / CH₂Cl₂ / 3 h

With methanol; sodium methylate; di(n-butyl)tin oxide; dimethyl-(methylthio)-sulphonium trifluoromethanesulphonate; In methanol; dichloromethane; 1.1: glycosylation / 2.1: debenzoylation / 3.1: Condensation;
DOI:10.1139/v00-081