(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(4-fluorobenzyl)iridium(III)

Base Information

Chemical Name:(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(4-fluorobenzyl)iridium(III)
CAS No.:1034979-65-1
Molecular Formula:C₅₅H₄₂FIrN₄
Molecular Weight:970.184
Hs Code.:

Synonyms:(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(4-fluorobenzyl)iridium(III)

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Chemical Property of (5,10,15,20-tetrakis(p-tolyl)porphyrinato)(4-fluorobenzyl)iridium(III)

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Technology Process of (5,10,15,20-tetrakis(p-tolyl)porphyrinato)(4-fluorobenzyl)iridium(III)

There total 3 articles about (5,10,15,20-tetrakis(p-tolyl)porphyrinato)(4-fluorobenzyl)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 352-32-9
p-fluorotoluene

: 872415-81-1
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

: 1034979-65-1
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(4-fluorobenzyl)iridium(III)

Guidance literature:: With NaOC₆H₅; In neat (no solvent); (under N2); Ir-complex, NaOC6H5 and 4-fluorotoluene heated at 200°C for 12 h;
DOI:10.1021/om700751h

Reference yield: 54.0%

: 872415-81-1
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride

: 459-46-1
4-Fluorobenzyl bromide

: 1034979-65-1
(5,10,15,20-tetrakis(p-tolyl)porphyrinato)(4-fluorobenzyl)iridium(III)

Guidance literature:: With NaBH₄; In tetrahydrofuran; sodium hydroxide; aq. NaOH; (under N2); soln. of NaBH4 in aq. NaOH added to suspn. of Ir-complex in THF, heated at 70°C for 2 h, cooled to room temp., ligand added, heated at 70°C for 2 h; extd. with CH2Cl2/H2O, dried over MgSO4, filtered, dried by rotary evaporator, alumina column chromy. with CH2Cl2-hexane (1:2), collected by rotary evaporator, recrystd. from CH2Cl2/MeOH;
DOI:10.1021/om700751h