chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III)

Base Information

• Chemical Name: chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III)
• CAS No.: 872415-81-1
• Molecular Formula: C₄₉H₃₆ClIrN₄O
• Molecular Weight: 924.524
• Mol file: 872415-81-1.mol

Synonyms:chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III)

Chemical Property of chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III)

There total 5 articles about chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + 5,10,15,20-tetra(p-tolyl)porphyrin (14527-51-6) → chloro(5,10,15,20-tetratolylporphyrinato)carbonyliridium(III) (872415-81-1)

Guidance literature:

In 5,5-dimethyl-1,3-cyclohexadiene; for 96h; Reflux;

DOI:10.1016/j.poly.2018.07.035

Reference yield: 67.0%

(hydrido)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (105139-33-1) + chlorobenzene (108-90-7) → (5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride (872415-81-1) + phenyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1224699-27-7)

Guidance literature:

In benzene-d6; heating of IrH(C20H8N4(p-tol)4), PhCl(50 equiv.) and benzene-d6 in a sealed NMR tube at 200°C for 4 ds; monitoring by NMR, chromy.;

DOI:10.1021/om200618m

Reference yield: 66.0%

bis(1,5-cyclooctadiene)diiridium(I) dichloride (12112-67-3) + 5,10,15,20-tetrakis(4-methylphenyl)porphyrin → (5,10,15,20-tetrakis(p-tolyl)porphyrinato)carbonyliridium(III) chloride (872415-81-1)

Guidance literature:

In xylene; soln. (Ir(COD)Cl)2 and porphyrin in xylene was refluxed for 3 days; react. mixt. was dried under high vac. and purified by silica chromy. (hexane-CH2Cl2 4:1), recrystn. from CH2Cl2-MeOH; elem. anal.;

DOI:10.1021/om050661a

upstream raw materials:

bis(1,5-cyclooctadiene)diiridium(I) dichloride

(hydrido)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

chlorobenzene

5,10,15,20-tetra(p-tolyl)porphyrin

Downstream raw materials:

(5,10,15,20-tetra-p-tolylporphyrinato)[(4-methoxyphenyl)ethyl]iridium(III)

(5,10,15,20-tetratolylporphyrinato)(ethylformyl)iridium(III)

(5,10,15,20-tetratolylporphyrinato)(benzoyl)iridium(III) toluene

(5,10,15,20-tetratolylporphyrinato)(4-fluorobenzoyl)iridium(III) toluene