Tetrabutylammonium persulfate triple salt

Base Information

• Chemical Name: Tetrabutylammonium persulfate triple salt
• CAS No.: 104548-30-3
• Molecular Formula: C16H38K5NO18S4
• Molecular Weight: 355.539
• European Community (EC) Number: 629-520-1
• DSSTox Substance ID: DTXSID40584955
• Mol file: 104548-30-3.mol

Synonyms:Tetrabutylammonium persulfate triple salt;104548-30-3;hydrogen sulfate;oxido hydrogen sulfate;tetrabutylazanium;sulfate;hydroxy sulfate;IGMBKNUVZFAHJM-UHFFFAOYSA-I;DTXSID40584955;tetrabutylammonium peroxomonosulfate;AKOS025294011;N,N,N-Tributylbutan-1-aminium hydrogen sulfate sulfate 2-sulfodioxidan-1-ide (5/1/1/2)

Chemical Property of Tetrabutylammonium persulfate triple salt

Chemical Property:

• Melting Point: 144-146 °C
• PSA: 367.36000
• LogP: 4.95340
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 18
• Rotatable Bond Count: 60
• Exact Mass: 1630.24409870
• Heavy Atom Count: 107
• Complexity: 355

Purity/Quality:

98%,99%, ^*data from raw suppliers

OXONE? tetrabutylammonium salt technical, ~1.6% active oxygen basis ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 22-34-52
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.CCCC[N+](CCCC)(CCCC)CCCC.OS(=O)(=O)[O-].OS(=O)(=O)O[O-].OS(=O)(=O)O[O-].[O-]S(=O)(=O)[O-]
• Uses: Reagent for:Oxidation of Hantzsch 1,4-Dihydropyridines catalyzed by manganese(III) Schiff Base complexesEpoxidation of alkenesOxidation of sulfides and olefinsOxidation of alcoholsOxidation of aromatic amines for synthesis of azoxy arenes

Technology Process of Tetrabutylammonium persulfate triple salt

There total 2 articles about Tetrabutylammonium persulfate triple salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.5%

tetra(n-butyl)ammonium hydrogensulfate (32503-27-8) → tetra-n-butylammonium hydrogen monopersulfate (104548-30-3)

Guidance literature:

With potassium sulfate; potassium hydrogensulfate; potassium peroxomonosulfate; In water; for 0.5h; Ambient temperature;

DOI:10.1021/jo00238a011

Reference yield:

tetra(n-butyl)ammonium hydrogensulfate (32503-27-8) → tetrabutylammonium monopersulfate (104548-30-3)

Guidance literature:

With potassium peroxomonosulfate; In water;

DOI:10.1142/S1088424610002136

Reference yield: 20.0%

Os(VIII) + (E)-1,2-diphenyl-ethene (103-30-0) + tetra-n-butylammonium hydrogen monopersulfate (104548-30-3) → benzaldehyde (100-52-7) + benzoic acid (65-85-0,8013-63-6)

Guidance literature:

With sodium sulfate; OsO₄; In methanol; dichloromethane; tert-butyl alcohol;

upstream raw materials:

tetra(n-butyl)ammonium hydrogensulfate

Downstream raw materials:

benzaldehyde

benzoic acid

(manganese(IV)tetraphenylporphyrin)(imidazole)(O)

[Mn(meso-tetrakis(pentafluorophenyl)porphyrinato)(acetato)2]^(1-)

Refernces

• 1、 Aghabali, Amineh,Safari, Nasser. "Effects of methoxy-substituted metalloporphyrins in catalytic alkene epoxidation by n-Bu 4NHSO 5". body text. p. 335 - 342. Retrieved 2010/11/21.