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2-METHYLNAPHTHALENE-1-BORONIC ACID

Base Information Edit
  • Chemical Name:2-METHYLNAPHTHALENE-1-BORONIC ACID
  • CAS No.:103989-84-0
  • Molecular Formula:C11H11 B O2
  • Molecular Weight:186.018
  • Hs Code.:2931900090
  • DSSTox Substance ID:DTXSID50464698
  • Nikkaji Number:J1.133.061D
  • Wikidata:Q82290133
  • Mol file:103989-84-0.mol
2-METHYLNAPHTHALENE-1-BORONIC ACID

Synonyms:1-Naphthaleneboronicacid, 2-methyl- (6CI); Boronic acid, (2-methyl-1-naphthalenyl)- (9CI);(2-Methyl-1-naphthalenyl)boronic acid; 2-Methyl-1-naphthaleneboronic acid;2-Methyl-1-naphthylboronic acid

Suppliers and Price of 2-METHYLNAPHTHALENE-1-BORONIC ACID
Supply Marketing:Edit
Business phase:
The product has achieved commercial mass production*data from LookChem market partment
Manufacturers and distributors:
  • Manufacture/Brand
  • Chemicals and raw materials
  • Packaging
  • price
  • Usbiological
  • 2-Methylnaphthalene-1-boronic acid
  • 500mg
  • $ 885.00
  • TRC
  • (2-Methylnaphthalen-1-yl)boronicAcid
  • 100mg
  • $ 90.00
  • Matrix Scientific
  • 2-Methyl-1-naphthylboronicacid 97%
  • 1g
  • $ 859.00
  • Crysdot
  • (2-Methylnaphthalen-1-yl)boronicacid 97%
  • 5g
  • $ 660.00
  • Chemenu
  • 2-Methyl-1-naphthylboronicacid 0.95
  • 500g
  • $ 130.00
  • Atlantic Research Chemicals
  • 2-Methyl-1-naphthylboronicacid 95%
  • 1gm:
  • $ 356.99
  • Apolloscientific
  • (2-methylnaphthalen-1-yl)boronic acid
  • 1g
  • $ 750.00
  • American Custom Chemicals Corporation
  • 2-METHYLNAPHTHALENE-1-BORONIC ACID 95.00%
  • 1G
  • $ 704.55
  • American Custom Chemicals Corporation
  • 2-METHYLNAPHTHALENE-1-BORONIC ACID 95.00%
  • 5MG
  • $ 504.70
  • Ambeed
  • 2-Methylnaphthalene-1-boronicAcid 98%
  • 5g
  • $ 512.00
Total 25 raw suppliers
Chemical Property of 2-METHYLNAPHTHALENE-1-BORONIC ACID Edit
Chemical Property:
  • Vapor Pressure:6.59E-07mmHg at 25°C 
  • Melting Point:126℃ 
  • Refractive Index:1.623 
  • Boiling Point:393.8°C at 760 mmHg 
  • PKA:8.87±0.30(Predicted) 
  • Flash Point:192°C 
  • PSA:40.46000 
  • Density:1.18g/cm3 
  • LogP:0.82800 
  • Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C 
  • Hydrogen Bond Donor Count:2
  • Hydrogen Bond Acceptor Count:2
  • Rotatable Bond Count:1
  • Exact Mass:186.0852098
  • Heavy Atom Count:14
  • Complexity:196
Purity/Quality:

97% *data from raw suppliers

2-Methylnaphthalene-1-boronic acid *data from reagent suppliers

Safty Information:
  • Pictogram(s):  
  • Hazard Codes: 
MSDS Files:

SDS file from LookChem

Useful:
  • Canonical SMILES:B(C1=C(C=CC2=CC=CC=C12)C)(O)O
Technology Process of 2-METHYLNAPHTHALENE-1-BORONIC ACID

There total 8 articles about 2-METHYLNAPHTHALENE-1-BORONIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
1-bromo-2-methylnaphtalene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h;
With Trimethyl borate; In tetrahydrofuran; at -78 ℃; for 0.5h;
DOI:10.1055/s-2003-38352
Guidance literature:
With hydrogenchloride; In tetrahydrofuran; treatment of naphthalene deriv. with butyllithium in THF, treatment withtrimethoxyborane, treatment with HCl; Malkov A.V., Dufkova L., Farrugia L., Kocovsky P. Angew. Chem., Int. Ed. 2003, 42, 3674;
DOI:10.1021/ja711338q
Guidance literature:
1-bromo-2-methylnaphtalene; With magnesium; In tetrahydrofuran; at 20 ℃; for 1h; Heating;
Triisopropyl borate; In tetrahydrofuran; at -78 - 20 ℃; for 18h;
With water; In tetrahydrofuran; for 1h;
DOI:10.1016/j.tet.2018.07.048
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