Methyl 5-(bromomethyl)-3-methoxy-2-(methoxycarbonyl)benzeneacetate

Base Information

• Chemical Name: Methyl 5-(bromomethyl)-3-methoxy-2-(methoxycarbonyl)benzeneacetate
• CAS No.: 137787-61-2
• Molecular Formula: C₁₃H₁₅BrO₅
• Molecular Weight: 331.163
• DSSTox Substance ID: DTXSID001166479

Synonyms:DTXSID001166479;Methyl 5-(bromomethyl)-3-methoxy-2-(methoxycarbonyl)benzeneacetate;137787-61-2

Chemical Property of Methyl 5-(bromomethyl)-3-methoxy-2-(methoxycarbonyl)benzeneacetate

Chemical Property:

• XLogP3: 2.1
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 7
• Exact Mass: 330.01029
• Heavy Atom Count: 19
• Complexity: 320

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: COC1=CC(=CC(=C1C(=O)OC)CC(=O)OC)CBr

Technology Process of Methyl 5-(bromomethyl)-3-methoxy-2-(methoxycarbonyl)benzeneacetate

There total 1 articles about Methyl 5-(bromomethyl)-3-methoxy-2-(methoxycarbonyl)benzeneacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

methyl 2-carbomethoxy-3-methoxy-5-methylbenzene-1-acetate (93953-37-8) → dimethyl-5-bromomethyl-3-methoxyhomophthalate (137787-61-2)

Guidance literature:

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); In tetrachloromethane; for 2h;

DOI:10.1016/S0040-4039(00)93465-8

Reference yield: 96.0%

dimethyl-5-bromomethyl-3-methoxyhomophthalate (137787-61-2) → 2-Carboxymethyl-4-hydroxymethyl-6-methoxy-benzoic acid (118991-80-3)

Guidance literature:

With potassium hydroxide; In methanol; for 3h; Heating;

DOI:10.1039/c39880001200

Reference yield: 83.0%

dimethyl-5-bromomethyl-3-methoxyhomophthalate (137787-61-2) → dimethyl-5-formyl-3-methoxyhomophthalate (137787-62-3)

Guidance literature:

With tetra(n-butyl)ammonium dichromate(VI); In chloroform; for 2h; Heating;

DOI:10.1016/S0040-4020(01)85666-0

upstream raw materials:

methyl 2-carbomethoxy-3-methoxy-5-methylbenzene-1-acetate

Downstream raw materials:

dimethyl-5-formyl-3-methoxyhomophthalate

2-Carboxymethyl-4-hydroxymethyl-6-methoxy-benzoic acid

2-Methoxy-6-(2-oxo-propyl)-4-[(Z)-2-(1,4,6,7-tetramethoxy-9-oxo-9H-xanthen-3-yl)-vinyl]-benzoic acid

2-Methoxy-6-(2-oxo-propyl)-4-[(Z)-2-(1,4,6,7-tetramethoxy-9-oxo-9H-xanthen-3-yl)-vinyl]-benzoic acid methyl ester

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 137787-61-2 dimethyl-5-bromomethyl-3-methoxyhomophthalate

Send

Send

Metric Ton KG G Pound L ML

Send

Send