2-Benzyloxybenzylbromide

Base Information

Chemical Name:2-Benzyloxybenzylbromide
CAS No.:103633-30-3
Molecular Formula:C14H13 Br O
Molecular Weight:277.161
Hs Code.:2909309090
DSSTox Substance ID:DTXSID50363814
Wikidata:Q72441782
Mol file:103633-30-3.mol

Synonyms:103633-30-3;2-BENZYLOXYBENZYLBROMIDE;1-(benzyloxy)-2-(bromomethyl)benzene;1-(bromomethyl)-2-phenylmethoxybenzene;1-(BENZYLOXY)-2-(BROMOMETHYL) BENZENE;2-benzyloxybenzyl bromide;2-(benzyloxy)benzylbromide;2-benzyloxy benzyl bromide;Benzene, 1-(bromomethyl)-2-(phenylmethoxy)-;o-(benzyloxy)benzyl bromide;SCHEMBL561222;2-bromomethylphenyl benzyl ether;DTXSID50363814;1-benzyloxy-2-bromomethyl-benzene;MFCD04038510;AKOS009310667;AS-44454;EN300-1868879;TRIMETHYLSILYL2-(FLUOROSULFONYL)DIFLUOROACETATE

Suppliers and Price of 2-Benzyloxybenzylbromide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
1-(Benzyloxy)-2-(bromomethyl)benzene
100mg
$ 200.00

Crysdot
1-(Benzyloxy)-2-(bromomethyl)benzene 95+%
5g
$ 1956.00

Crysdot
1-(Benzyloxy)-2-(bromomethyl)benzene 95+%
1g
$ 651.00

Biosynth Carbosynth
2-Benzyloxybenzylbromide
500 mg
$ 380.00

Biosynth Carbosynth
2-Benzyloxybenzylbromide
250 mg
$ 217.50

Biosynth Carbosynth
2-Benzyloxybenzylbromide
100 mg
$ 109.00

Biosynth Carbosynth
2-Benzyloxybenzylbromide
50 mg
$ 63.00

Biosynth Carbosynth
2-Benzyloxybenzylbromide
1 g
$ 661.00

American Custom Chemicals Corporation
2-BENZYLOXYBENZYLBROMIDE 95.00%
5G
$ 2152.64

American Custom Chemicals Corporation
2-BENZYLOXYBENZYLBROMIDE 95.00%
1G
$ 1009.01

Total 11 raw suppliers

Chemical Property of 2-Benzyloxybenzylbromide

Chemical Property:

Melting Point:40-42 °C
Boiling Point:354.9±22.0 °C(Predicted)
PSA：9.23000
Density:1.361±0.06 g/cm3(Predicted)
LogP:4.16050
Storage Temp.:Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
XLogP3:3.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:276.01498
Heavy Atom Count:16
Complexity:189

Purity/Quality:

99% ^*data from raw suppliers

1-(Benzyloxy)-2-(bromomethyl)benzene ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)COC2=CC=CC=C2CBr

Technology Process of 2-Benzyloxybenzylbromide

There total 15 articles about 2-Benzyloxybenzylbromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 3381-87-1
2-benzyloxybenzyl alcohol

: 103633-30-3
2-bromomethylphenyl benzyl ether

Guidance literature:: With phosphorus tribromide; In toluene;
DOI:10.1016/S0031-9422(97)00955-2

Reference yield:

: 5896-17-3
2-(phenylmethoxy)benzaldehyde

: 103633-30-3
2-bromomethylphenyl benzyl ether

Guidance literature:: Multi-step reaction with 2 steps

1: 98 percent / NaBH₄ / methanol / 0.5 h / 20 °C

2: 88 percent / PPh₃; CBr₄ / CH₂Cl₂ / 0.5 h

With sodium tetrahydroborate; carbon tetrabromide; triphenylphosphine; In methanol; dichloromethane;
DOI:10.1021/jm051060o

Reference yield:

: 89-95-2
2-methyl-benzyl alcohol

: 103633-30-3
2-bromomethylphenyl benzyl ether

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / K₂CO₃ / acetone / 5 h / Heating

2: 98 percent / NaBH₄ / methanol / 0.5 h / 20 °C

3: 88 percent / PPh₃; CBr₄ / CH₂Cl₂ / 0.5 h

With sodium tetrahydroborate; carbon tetrabromide; potassium carbonate; triphenylphosphine; In methanol; dichloromethane; acetone;
DOI:10.1021/jm051060o