1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose

Base Information

Chemical Name:1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose
CAS No.:97321-49-8
Molecular Formula:C₁₆H₂₂O₆S
Molecular Weight:342.413
Hs Code.:

Synonyms:1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose

Suppliers and Price of 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose

There total 10 articles about 1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.5%

: 81076-80-4
1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-4-O-mesyl-β-D-galactopyranose

: 81076-81-5
1,6-anhydro-3-O-benzyl-2,4-dideoxy-2-C-methyl-4-methylene-β-D-xylohexopyranose

: 97321-49-8
1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose

Guidance literature:: With 4 A molecular sieve; In nitromethane; for 20h; Heating;
DOI:10.1007/BF01142801

Reference yield:

: 91510-64-4
4-O-allyl-1,6-anhydro-2-deoxy-2-C-methyl-β-D-glucopyranose

: 97321-49-8
1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) sodium hydride / 1.) DMF, 20 deg C, 1 h; 2.) DMF, 20 deg C, 0.5 h

2: 1.) potassium tert-butoxide; 2.) mercury(II) oxide, mercury(II) chloride / 1.) methyl sulfoxide, 100 deg C, 1 h; 2.) acetone, water

3: 98.5 percent / methyl sulfoxide, oxalyl chloride / CH₂Cl₂ / 0.25 h / -60 °C

4: 1.) butyl-lithium / 1.) hexane, benzene, 15 min; 2.) hexane, benzene, reflux, 10 min

5: m-chloroperoxybenzoic acid / CHCl₃ / 1 h / Heating

6: lithium aluminum hydride / tetrahydrofuran / 0.17 h

7: 82 percent / pyridine / CH₂Cl₂ / Ambient temperature

8: 58.5 percent / molecular sieves 4 Angstroem / nitromethane / 20 h / Heating

With pyridine; lithium aluminium tetrahydride; n-butyllithium; oxalyl dichloride; 4 A molecular sieve; potassium tert-butylate; sodium hydride; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; mercury dichloride; mercury(II) oxide; In tetrahydrofuran; nitromethane; dichloromethane; chloroform;
DOI:10.1016/0008-6215(85)85189-2

Reference yield:

: 81076-77-9
1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-β-D-galactopyranose

: 97321-49-8
1,6-anhydro-2-desoxy-2,4-di-C-methyl-3-O-benzyl-5-O-mesyl-α-L-idofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 82 percent / pyridine / CH₂Cl₂ / Ambient temperature

2: 58.5 percent / molecular sieves 4 Angstroem / nitromethane / 20 h / Heating

With pyridine; 4 A molecular sieve; In nitromethane; dichloromethane;
DOI:10.1016/0008-6215(85)85189-2