(2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime

Base Information

Chemical Name:(2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime
CAS No.:1397274-90-6
Molecular Formula:C₁₃H₁₅ClN₂O₈
Molecular Weight:362.724
Hs Code.:

Synonyms:(2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime

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Chemical Property of (2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime

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Technology Process of (2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime

There total 9 articles about (2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1397274-89-3
(2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime

: 1397274-90-6
(2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime

Guidance literature:: (2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime; With sodium methylate; In methanol; dichloromethane; at 20 ℃; for 10h;

In methanol; dichloromethane;
DOI:10.1021/ol3023374

Reference yield:

: 1397274-88-2
(2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-glucopyranoside

: 1397274-90-6
(2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime

Guidance literature:: Multi-step reaction with 3 steps

1.1: Dess-Martin periodane / dichloromethane / 2 h / 20 °C / Inert atmosphere

2.1: pyridine / 2 h / 20 °C

3.1: sodium methylate / dichloromethane; methanol / 10 h / 20 °C

3.2: Amberlite IR-120 (H+ form)

With pyridine; sodium methylate; Dess-Martin periodane; In methanol; dichloromethane;
DOI:10.1021/ol3023374

Reference yield:

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 1397274-90-6
(2-chloro-4-nitrophenyl) 2,3,4-tri-O-benzoyl-β-D-gluco-hexodialdo-1,5-pyranose-6-O-methyloxime

Guidance literature:: Multi-step reaction with 8 steps

1.1: tetrabutylammomium bromide; sodium hydroxide / dichloromethane / 18 h / 20 °C

2.1: sodium methylate / methanol / 18 h / 20 °C

2.2: Amberlite IR-120 (H+ form)

3.1: 1H-imidazole / N,N-dimethyl-formamide / 48 h / 20 °C

4.1: pyridine / 16 h / 20 °C

5.1: acetyl chloride; methanol / diethyl ether / 40 h / 20 °C

6.1: Dess-Martin periodane / dichloromethane / 2 h / 20 °C / Inert atmosphere

7.1: pyridine / 2 h / 20 °C

8.1: sodium methylate / dichloromethane; methanol / 10 h / 20 °C

8.2: Amberlite IR-120 (H+ form)

With pyridine; 1H-imidazole; methanol; tetrabutylammomium bromide; sodium methylate; Dess-Martin periodane; acetyl chloride; sodium hydroxide; In methanol; diethyl ether; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ol3023374