Nickel(2+);trimethylphosphane;dichloride

Base Information

Chemical Name:Nickel(2+);trimethylphosphane;dichloride
CAS No.:103421-62-1
Molecular Formula:C₆H₁₈Cl₂NiP₂
Molecular Weight:281.752
Hs Code.:
Mol file:103421-62-1.mol

Synonyms:

Suppliers and Price of Nickel(2+);trimethylphosphane;dichloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 2 raw suppliers

Chemical Property of Nickel(2+);trimethylphosphane;dichloride

Chemical Property:

Vapor Pressure:434mmHg at 25°C
Melting Point:194-199 °C(lit.)
Boiling Point:40.5°C at 760 mmHg
PSA：27.18000
LogP:4.09440
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:0
Exact Mass:279.961422
Heavy Atom Count:11
Complexity:8

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 20/21/22
Safety Statements: 36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CP(C)C.CP(C)C.[Cl-].[Cl-].[Ni+2]

Technology Process of Nickel(2+);trimethylphosphane;dichloride

There total 2 articles about Nickel(2+);trimethylphosphane;dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 83864-14-6
nickel dichloride

: 594-09-2
trimethylphosphane

: 103421-62-1,19232-05-4,20087-67-6
trans-[dichlorobis(trimethylphosphane)nickel(II)]

Guidance literature:: In tetrahydrofuran; at 90 ℃; for 20h; Inert atmosphere;
DOI:10.1021/acs.organomet.0c00708

Reference yield:

: 29046-78-4
(1,2-dimethoxyethane)dichloronickel(II)

: 594-09-2
trimethylphosphane

: 103421-62-1,19232-05-4,20087-67-6
trans-[dichlorobis(trimethylphosphane)nickel(II)]

Guidance literature:: In tetrahydrofuran; toluene; Inert atmosphere;
DOI:10.1002/ejic.202101006

Reference yield: 87.0%

: 103421-62-1,19232-05-4,20087-67-6
trans-[dichlorobis(trimethylphosphane)nickel(II)]

: 65423-44-1
(2-diphenylphosphino)benzeneamine

: Ni(II)Cl₂P(CH₃)3 (o-diphenylphosphino)aniline

Guidance literature:: In dichloromethane; org. compd. (solid) addn. to Ni-compd. soln., stirring (1 h, room temp., under N2), concn., pptn. on n-hexane addn.; solid filtration off, washing (n-hexane, C6H6 and Et2O), vac. drying;
DOI:10.1021/ja9738440