C₃₇H₆₄O₆Si₂

Base Information

Chemical Name:C₃₇H₆₄O₆Si₂
CAS No.:1103963-61-6
Molecular Formula:C₃₇H₆₄O₆Si₂
Molecular Weight:661.083
Hs Code.:

C<sub>37</sub>H<sub>64</sub>O<sub>6</sub>Si<sub>2</sub>

Synonyms:C₃₇H₆₄O₆Si₂

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Chemical Property of C₃₇H₆₄O₆Si₂

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Technology Process of C₃₇H₆₄O₆Si₂

There total 14 articles about C₃₇H₆₄O₆Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1103963-58-1
(3S,4S,5R,6S,7S,8E,10E)-3,4-bis(tert-butyldimethylsilyloxy)-5,7-dihydroxy-6,8,10-trimethyldodeca-8,10-dienyl benzoate

: 77-76-9
2,2-dimethoxy-propane

: 1103963-61-6
C₃₇H₆₄O₆Si₂

Guidance literature:: With camphor-10-sulfonic acid; In N,N-dimethyl-formamide; at 20 ℃; for 2h;
DOI:10.1002/anie.200803271

Reference yield:

: (4S,5R)-4-(2-(benzyloxy)ethyl)-5-(2-methoxybenzoyl)-1,3-dioxolan-2-one

: 1103963-61-6
C₃₇H₆₄O₆Si₂

Guidance literature:: Multi-step reaction with 9 steps

1: sodium dihydrogenphosphate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 5 h / 40 °C / Inert atmosphere

2: sodium bis(2-methoxyethoxy)aluminium dihydride / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere

3: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

4: sodium periodate; rhodium(III) chloride hydrate / acetonitrile; water / 5 h / 20 °C / Inert atmosphere

5: (1S)-10-camphorsulfonic acid / ethanol / 27 h / 0 °C / Inert atmosphere

6: [bis(acetoxy)iodo]benzene; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / dichloromethane / 12 h / 0 - 20 °C / Inert atmosphere

7: boron trifluoride diethyl etherate / dichloromethane / 2.5 h / -40 °C / Inert atmosphere

8: diethyl methoxy borane; sodium tetrahydroborate / methanol; tetrahydrofuran / 3 h / -30 °C / Inert atmosphere

9: (1S)-10-camphorsulfonic acid / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

With 2,6-dimethylpyridine; sodium tetrahydroborate; sodium periodate; sodium dihydrogenphosphate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; rhodium(III) chloride hydrate; diethyl methoxy borane; boron trifluoride diethyl etherate; (1S)-10-camphorsulfonic acid; 3-chloro-benzenecarboperoxoic acid; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; 1: |Baeyer-Villiger Ketone Oxidation / 7: |Mukaiyama Aldol Addition;
DOI:10.1002/chem.201304297

Reference yield:

: (4R,5S)-2-methoxyphenyl 5-(2-(benzyloxy)ethyl)-2-oxo-1,3-dioxolane-4-carboxylate

: 1103963-61-6
C₃₇H₆₄O₆Si₂

Guidance literature:: Multi-step reaction with 8 steps

1: sodium bis(2-methoxyethoxy)aluminium dihydride / tetrahydrofuran; toluene / 0.5 h / 0 °C / Inert atmosphere

2: 2,6-dimethylpyridine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

3: sodium periodate; rhodium(III) chloride hydrate / acetonitrile; water / 5 h / 20 °C / Inert atmosphere

4: (1S)-10-camphorsulfonic acid / ethanol / 27 h / 0 °C / Inert atmosphere

5: [bis(acetoxy)iodo]benzene; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical / dichloromethane / 12 h / 0 - 20 °C / Inert atmosphere

6: boron trifluoride diethyl etherate / dichloromethane / 2.5 h / -40 °C / Inert atmosphere

7: diethyl methoxy borane; sodium tetrahydroborate / methanol; tetrahydrofuran / 3 h / -30 °C / Inert atmosphere

8: (1S)-10-camphorsulfonic acid / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

With 2,6-dimethylpyridine; sodium tetrahydroborate; sodium periodate; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; rhodium(III) chloride hydrate; diethyl methoxy borane; boron trifluoride diethyl etherate; (1S)-10-camphorsulfonic acid; sodium bis(2-methoxyethoxy)aluminium dihydride; In tetrahydrofuran; methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; toluene; acetonitrile; 6: |Mukaiyama Aldol Addition;
DOI:10.1002/chem.201304297