PROPYL-D7 ALCOHOL

Base Information

• Chemical Name: PROPYL-D7 ALCOHOL
• CAS No.: 102910-31-6
• Molecular Formula: C3H D7 O
• Molecular Weight: 67.14
• Hs Code.: 2905121000
• Mol file: 102910-31-6.mol

Synonyms:1-PROPANOL-1,1,2,2,3,3,3-D7;N-PROPANOL (D7);PROPANOL-D7;PROPYL-D7 ALCOHOL;PROPYL-D7 ALCOHOL 98%;1-propan-d7-ol;1-Propan-d7-ol, Propyl-d7 alcohol

Chemical Property of PROPYL-D7 ALCOHOL

Chemical Property:

• Melting Point: -127 °C(lit.)
• Boiling Point: 97 °C(lit.)
• PSA: 20.23000
• Density: 0.896 g/mL at 25oC
• LogP: 0.38870

Purity/Quality:

99% ^*data from raw suppliers

1-Propan-1,1,2,2,3,3,3-d7-ol ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 11-41-67
• Safety Statements: 7-16-24-26-39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of PROPYL-D7 ALCOHOL

There total 4 articles about PROPYL-D7 ALCOHOL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Propiolsaeure (3634-35-3) → <1,1,1,2,2,3,3-D7>-Propanol (102910-31-6) + 1,1,2,3,3-pentadeuteroallyl alcohol (102910-30-5)

Guidance literature:

With lithium aluminium deuteride; In diethyl ether; at 5 ℃; for 6h; Yield given. Yields of byproduct given;

DOI:10.1055/s-1985-31344

Reference yield:

d5-ethyl propionate (1265919-32-1) → <1,1,1,2,2,3,3-D7>-Propanol (102910-31-6)

Guidance literature:

d5-ethyl propionate; With lithium aluminium deuteride; In diethyl ether; at 20 ℃; for 3h;

With water-d2; In diethyl ether; at 20 ℃; for 1h;

With sulfuric acid; In diethyl ether; pH=4 - 5;

Reference yield:

propionic acid-d5 (60153-92-6) → <1,1,1,2,2,3,3-D7>-Propanol (102910-31-6)

Guidance literature:

With lithium aluminium deuteride; water; Multistep reaction;

DOI:10.1021/j100084a043

upstream raw materials:

Propiolsaeure

propionic acid-d5

d5-ethyl propionate

Downstream raw materials:

(1-2H₂,2-2H₂,3-2H₃)-iodopropane

Refernces

• 1、 Poeschl, M.,Hertz, H. G.. "Intramolecular Thermal Motions in Liquid n-Propanol (+ Glycerol), A Proton Magnetic Relaxation Study. 2". . p. 8195 - 8208. Retrieved 1994.
• 2、 Thiem, Joachim,Mohn, Holger,Heesing, Albert. "Anwendung der Perdeuteroallyl Schutz-Gruppe". . p. 775 - 778. Retrieved 2007/10/02.