2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane

Base Information

Chemical Name:2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane
CAS No.:87729-26-8
Molecular Formula:C₁₆H₂₀O₃
Molecular Weight:260.333
Hs Code.:

Synonyms:2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane

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Technology Process of 2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane

There total 2 articles about 2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

: 87760-80-3
6-endo-Hydroxy-2-endo-(hydroxymethyl)-3-exo-methylbicyclo<2.2.1>heptane

: 98-88-4
benzoyl chloride

: Benzoic acid (1S,2S,4R,6R)-6-hydroxymethyl-6-methyl-bicyclo[2.2.1]hept-2-yl ester

: 87729-26-8
2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane

: 87729-25-7
C₂₃H₂₄O₄

Guidance literature:: With pyridine; In diethyl ether; at -20 ℃; for 2h;
DOI:10.1021/jo00177a015

Reference yield:

: 38335-10-3
(+/-)-3-methyl-hexahydro-3,5-methano-cyclopenta[b]furan-2-one

: 87729-26-8
2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane

Guidance literature:: Multi-step reaction with 2 steps

1: 99 percent / LiAlH₄ / diethyl ether; tetrahydrofuran / 1.) 0 deg C, 2.) 18 h, room temperature

2: 47 percent / Pyridine / diethyl ether / 2 h / -20 °C

With pyridine; lithium aluminium tetrahydride; In tetrahydrofuran; diethyl ether;
DOI:10.1021/jo00177a015

Reference yield: 14.0%

: 87729-26-8
2-endo-<(Benzoyloxy)methyl>-6-endo-hydroxy-2-exo-methylbicyclo<2.2.1>heptane

: 65-85-0,8013-63-6
benzoic acid

: 87729-25-7
6-exo-(Benzoyloxy)-2-endo-<(benzoyloxy)methyl>-2-exo-methylbicyclo<2.2.1>heptane

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In benzene; at 60 - 65 ℃; for 3h; Further byproducts given;
DOI:10.1021/jo00177a015