4-Methoxy-benzeneselenol anion

Base Information

• Chemical Name: 4-Methoxy-benzeneselenol anion
• CAS No.: 87137-05-1
• Molecular Formula: C₇H₇OSe
• Molecular Weight: 186.092
• Mol file: 87137-05-1.mol

Synonyms:4-Methoxy-benzeneselenol anion

Chemical Property of 4-Methoxy-benzeneselenol anion

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-Methoxy-benzeneselenol anion

There total 2 articles about 4-Methoxy-benzeneselenol anion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-methoxyphenyl methyl selenide (1694-07-1) + diphenyl diselenide (1666-13-3) → selenoanisole (4346-64-9) + 4-Methoxy-benzeneselenol anion (87137-05-1)

Guidance literature:

With sodium tetrahydroborate; In sulfolane; at 90 ℃; Equilibrium constant;

DOI:10.1021/ja00241a036

Reference yield:

bis(4-methoxyphenyl)diselenide (38762-70-8) → 4-Methoxy-benzeneselenol anion (87137-05-1)

Guidance literature:

With sodium tetrahydroborate; In tetrahydrofuran; ethanol; Inert atmosphere;

DOI:10.1016/j.bmc.2020.115423

Reference yield:

4-Methoxy-benzeneselenol anion (87137-05-1) + methyl phenyl selenone (98750-90-4) → selenoanisole (4346-64-9) + 4-methoxyphenyl methyl selenide (1694-07-1) + diphenylselenide (1132-39-4) + diphenyl diselenide (1666-13-3)

Guidance literature:

In tetrahydrofuran; ethanol; at 0 ℃; for 1h; Mechanism; various perfluoroalkyl phenyl selenones and selenoxides;

DOI:10.1016/S0022-1139(00)83744-6

upstream raw materials:

4-methoxyphenyl methyl selenide

diphenyl diselenide

bis(4-methoxyphenyl)diselenide

Downstream raw materials:

4-methoxyphenyl methyl selenide

benzeneselenolate ion

diphenyl diselenide

phenyl trifluoromethylselenide

Refernces