[C₆H₅S(O)CH₂]^(1-)*Li⁽¹⁺⁾=[C₆H₅S(O)CH₂]Li

Base Information

• Chemical Name: [C₆H₅S(O)CH₂]^(1-)*Li⁽¹⁺⁾=[C₆H₅S(O)CH₂]Li
• CAS No.: 59501-96-1
• Molecular Formula: C₇H₇OS*Li
• Molecular Weight: 146.139
• Mol file: 59501-96-1.mol

Synonyms:[C₆H₅S(O)CH₂]^(1-)*Li⁽¹⁺⁾=[C₆H₅S(O)CH₂]Li

Chemical Property of [C₆H₅S(O)CH₂]^(1-)*Li⁽¹⁺⁾=[C₆H₅S(O)CH₂]Li

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [C₆H₅S(O)CH₂]^(1-)*Li⁽¹⁺⁾=[C₆H₅S(O)CH₂]Li

There total 2 articles about [C₆H₅S(O)CH₂]^(1-)*Li⁽¹⁺⁾=[C₆H₅S(O)CH₂]Li which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Methyl p-tolyl sulfoxide (934-72-5) → [C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li (59501-96-1)

Guidance literature:

Methyl p-tolyl sulfoxide; With lithium diisopropyl amide; In diethyl ether; at -78 ℃; for 1h; Inert atmosphere; Schlenk technique;

In diethyl ether; at 20 ℃; for 0.75h; Inert atmosphere; Schlenk technique;

DOI:10.1039/C8DT03669A

Reference yield:

racemic methyl phenyl sulfoxide (1193-82-4) → [C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li (59501-96-1)

Guidance literature:

racemic methyl phenyl sulfoxide; With lithium diisopropyl amide; In diethyl ether; at -78 ℃; for 1h; Inert atmosphere; Schlenk technique;

In diethyl ether; at 20 ℃; for 0.75h; Inert atmosphere; Schlenk technique;

DOI:10.1039/C8DT03669A

Reference yield: 98.0%

[C6H5S(O)CH2](1-)*Li(1+)=[C6H5S(O)CH2]Li (59501-96-1) + (C5H5)Fe[P(OC6H5)3]2Cl (84430-52-4) → ferrocene (102-54-5,55404-68-7) + bis(phenylthio)methane (3561-67-9) + 1,2-bis(phenylthio)ethane (622-20-8) + diphenyldisulfane (882-33-7) + lithium chloride

Guidance literature:

In tetrahydrofuran; mixing reactants in THF at -78°C, slow warming to room temp. / further products; evapn. in vac., extn. with pentane, ether and finally acetone or CH2Cl2, concn., chromy. on Al2O3, purifn. by crystn., distn. or sublimation;

DOI:10.1016/S0022-328X(00)86902-8

upstream raw materials:

Methyl p-tolyl sulfoxide

racemic methyl phenyl sulfoxide

Downstream raw materials:

dimanganese decacarbonyl

racemic methyl phenyl sulfoxide

diphenyldisulfane

lithium bromide

Refernces