(S,R(p))-1-iodo-[(4-methylphenyl)sulfinyl]-ferrocene

Base Information

Chemical Name:(S,R(p))-1-iodo-[(4-methylphenyl)sulfinyl]-ferrocene
CAS No.:358721-79-6
Molecular Formula:C₁₇H₁₅FeIOS
Molecular Weight:450.123
Hs Code.:

Synonyms:(S,R(p))-1-iodo-[(4-methylphenyl)sulfinyl]-ferrocene

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Chemical Property of (S,R(p))-1-iodo-[(4-methylphenyl)sulfinyl]-ferrocene

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Technology Process of (S,R(p))-1-iodo-[(4-methylphenyl)sulfinyl]-ferrocene

There total 1 articles about (S,R(p))-1-iodo-[(4-methylphenyl)sulfinyl]-ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 130225-27-3,164297-25-0,238753-24-7
(S_S)-ferrocenyl p-tolylsulfoxide

: 7553-56-2,12190-71-5,8031-47-8
iodine

: 358721-79-6
(S,R(p))-1-iodo-[(4-methylphenyl)sulfinyl]-ferrocene

Guidance literature:: With diisopropylamine; n-BuLi; In tetrahydrofuran; hexane; to soln. i-Pr2NH in THF soln. n-BuLi in hexane was added dropwise at -25°C and stirred for 30 min, suspn. Fe complex in THF was added at -78°C and stirred for 30 min, soln. I2 in THF was added dropwise and stirred for 20 min; react. mixt. was quenched with water, extd. with Et2O, dried with MgSO4,solvent was removed in vacuo, residue was crystd. from CH2Cl2-hexane; e lem. anal.;
DOI:10.1039/b816544k

Reference yield: 90.0%

: 358721-79-6
(S,R(p))-1-iodo-[(4-methylphenyl)sulfinyl]-ferrocene

: 68572-87-2
9-phenanthrenylboronic acid

: (S,S)-2-(9-phenanthrenyl)-1-(p-tolylsulfinyl)ferrocene

Guidance literature:: With Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)₂Cl₂; caesium carbonate; In tetrahydrofuran; water; toluene; at 80 ℃; for 16h; Schlenk technique; Inert atmosphere;
DOI:10.1002/ejoc.201501121

Reference yield: 89.0%

: 358721-79-6
(S,R(p))-1-iodo-[(4-methylphenyl)sulfinyl]-ferrocene

: 100622-34-2
anthracene-9-boronic acid

: (S,S)-2-(9-anthracenyl)-1-(p-tolylsulfinyl)ferrocene

Guidance literature:: With Pd(2-dicyclohexylphosphino-2’,6’-dimethoxybiphenyl)₂Cl₂; caesium carbonate; In tetrahydrofuran; water; toluene; at 80 ℃; for 16h; Schlenk technique; Inert atmosphere;
DOI:10.1002/ejoc.201501121