METHYL (S)-(-)-4-BROMO-3-TERT-BUTYLDIMETHYLSILYLOXYBUTANOATE

Base Information

Chemical Name:METHYL (S)-(-)-4-BROMO-3-TERT-BUTYLDIMETHYLSILYLOXYBUTANOATE
CAS No.:101703-35-9
Molecular Formula:C11H23 Br O3 Si
Molecular Weight:311.29
Hs Code.:29310099
Mol file:101703-35-9.mol

Synonyms:Butanoicacid, 4-bromo-3-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, methyl ester, (S)-;4-Bromo-3-(S)-[(tert-butyldimethylsilanyl)oxy]butyric acid methyl ester

Suppliers and Price of METHYL (S)-(-)-4-BROMO-3-TERT-BUTYLDIMETHYLSILYLOXYBUTANOATE

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of METHYL (S)-(-)-4-BROMO-3-TERT-BUTYLDIMETHYLSILYLOXYBUTANOATE

Chemical Property:

Refractive Index:1.4565-1.4585
PSA：35.53000
LogP:3.33480
Storage Temp.:0-6°C

Purity/Quality:: 98%Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Safety Statements: 24/25

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of METHYL (S)-(-)-4-BROMO-3-TERT-BUTYLDIMETHYLSILYLOXYBUTANOATE

There total 2 articles about METHYL (S)-(-)-4-BROMO-3-TERT-BUTYLDIMETHYLSILYLOXYBUTANOATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 288-32-4
1H-imidazole

: 18162-48-6
tert-butyldimethylsilyl chloride

: 101703-35-9
4-bromo-3-(S)-(tert-butyl-dimethyl-silanyloxy)-butyric acid methyl ester

Guidance literature:: With hydrogenchloride; dmap; In N-methyl-acetamide;

Reference yield:

: 88759-56-2
(S)-bromo-3-hydroxybutyric acid methyl ester

: 18162-48-6
tert-butyldimethylsilyl chloride

: 101703-35-9
4-bromo-3-(S)-(tert-butyl-dimethyl-silanyloxy)-butyric acid methyl ester

Guidance literature:: With 1H-imidazole; dmap; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4039(00)98589-7

Reference yield:

: (+/-)-cis-N-(4-Chloro-phenyl)-N-[1-(4-hydroxy-benzoyl)-2-methyl-1,2,3,4-tetrahydro-quinolin-4-yl]-acetamide

: (2S,4R)-4-(4-{14-[Acetyl-(4-chloro-phenyl)-amino]-2-methyl-3,4-dihydro-2H-quinoline-carbonyl}-phenoxy)-3-(S)-(tert-butyl-dimethyl-silanyloxy)-butyric acid methyl ester

: (2S,4R)-4-(4-{4-[Acetyl-(4-chloro-phenyl)-amino]-2-methyl-3,4-dihydro-2H-quinoline-carbonyl}-phenoxy)-3-(S)-hydroxy-butyric acid methyl ester

: 429-41-4
tetrabutyl ammonium fluoride

: 101703-35-9
4-bromo-3-(S)-(tert-butyl-dimethyl-silanyloxy)-butyric acid methyl ester

: (2S,4R)-4-(4-{4-[Acetyl-(4-chloro-phenyl)-amino]-2-methyl-3,4-dihydro-2H-quinoline-1-carbonyl}-phenoxy)-3-(S)-hydroxy-butyric acid

Guidance literature:: With hydrogenchloride; LiOH; caesium carbonate; In tetrahydrofuran; methanol; water; 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran; ethyl acetate; N,N-dimethyl-formamide;