1-BROMO-2-METHYLHEXANE

Base Information

• Chemical Name: 1-BROMO-2-METHYLHEXANE
• CAS No.: 101258-57-5
• Molecular Formula: C7H15 Br
• Molecular Weight: 179.1
• Mol file: 101258-57-5.mol

Synonyms:1-Bromo-2-methylhexane

Chemical Property of 1-BROMO-2-METHYLHEXANE

Chemical Property:

• Refractive Index: 1.4339 (estimate)
• Boiling Point: 170.18°C (estimate)
• PSA: 0.00000
• Density: 1.1337 (estimate)
• LogP: 3.20760

Purity/Quality:

98%min ^*data from raw suppliers

1-BROMO-2-METHYLHEXANE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1-BROMO-2-METHYLHEXANE

There total 23 articles about 1-BROMO-2-METHYLHEXANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

2-methylhexan-1-ol (624-22-6) → 1-bromo-2-methylhexane (101258-57-5)

Guidance literature:

With hydrogen bromide; for 7h; Heating;

Reference yield: 88.0%

Toluene-4-sulfonic acid 2-methyl-hexyl ester (1188414-55-2) → 1-bromo-2-methylhexane (101258-57-5)

Guidance literature:

With sodium bromide; In dimethyl sulfoxide; for 120h;

Reference yield: 67.0%

(R)-2-methylhexyl 4-methylbenzenesulfonate (99824-63-2) → (R)-1-bromo-2-methylhexane (97424-48-1,101258-57-5,111555-12-5,111555-11-4)

Guidance literature:

With lithium bromide; In N,N-dimethyl-formamide; at 20 ℃;

DOI:10.1246/bcsj.75.111

upstream raw materials:

2-methylhexan-1-ol

Toluene-4-sulfonic acid 2-methyl-hexyl ester

2-methylhexanoic acid

butylmethylpropanedioic acid diethyl ester

Downstream raw materials:

(S)-3-methylheptan-1-ol

(R)-(+)-3-Methyl-1-heptanol

2-methylhexanal

C₃₃H₂₄F₁₂O

Refernces

• 1、 Hedenstroem, Erik,Andersson, Fredrik. "Syntheses of female sex pheromone precursors of pine sawfly species and of some structurally related methyl-branched long-chain 2-alkanols.". . p. 1237 - 1254. Retrieved 2002.
• 2、 Jarling, Rene,Sadeghi, Masih,Drozdowska, Marta,Lahme, Sven,Buckel, Wolfgang,Rabus, Ralf,Widdel, Friedrich,Golding, Bernard T.,Wilkes, Heinz. "Stereochemical investigations reveal the mechanism of the bacterial activation of n-alkanes without oxygen". supporting information; experimental part. p. 1334 - 1338. Retrieved 2012/03/27.