1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester

Base Information

Chemical Name:1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester
CAS No.:866412-83-1
Molecular Formula:C₁₄H₁₄O₄
Molecular Weight:246.263
Hs Code.:

Synonyms:1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester

Suppliers and Price of 1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester

There total 4 articles about 1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: dimethyl 2-benzylcycloprop-2-ene-1,1-dicarboxylate

: 866412-83-1
1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 20 ℃; for 5h; Inert atmosphere;
DOI:10.1016/j.tetlet.2013.04.076

Reference yield: 82.0%

: 6773-29-1
dimethyl diazomalonate

: 2327-99-3
1-phenylpropadiene

: 866412-83-1
1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester

Guidance literature:: With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;
DOI:10.1021/ol501676q

Reference yield: 70.0%

: 33992-52-8
(3-bromopropa-1,2-dien-1-yl)benzene

: 108-59-8
malonic acid dimethyl ester

: 866412-83-1
1-(methoxycarbonyl)-2-(phenylmethylene)cyclopropanecarboxylic acid methyl ester

: 2,5-Bis-methoxycarbonyl-3-[1-phenyl-meth-(E)-ylidene]-hexanedioic acid dimethyl ester

Guidance literature:: malonic acid dimethyl ester; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.25h;

(3-bromopropa-1,2-dien-1-yl)benzene; In tetrahydrofuran; at 55 ℃; for 28h;
DOI:10.1021/ol061993u