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Technology Process of (C6H5)3PNP(C6H5)3(1+)*W(CO)3(CH3)2PCH2CH2P(CH3)2SH(1-)=(C6H5)3PNP(C6H5)3W(CO)3(CH3)2PCH2CH2P(CH3)2SH

(C6H5)3PNP(C6H5)3(1+)*W(CO)3(CH3)2PCH2CH2P(CH3)2SH(1-)=(C6H5)3PNP(C6H5)3W(CO)3(CH3)2PCH2CH2P(CH3)2SH

Base Information
  • Chemical Name:(C6H5)3PNP(C6H5)3(1+)*W(CO)3(CH3)2PCH2CH2P(CH3)2SH(1-)=(C6H5)3PNP(C6H5)3W(CO)3(CH3)2PCH2CH2P(CH3)2SH
  • CAS No.:481657-96-9
  • Molecular Formula:C9H17O3P2SW*C36H30NP2
  • Molecular Weight:989.684
  • Hs Code.:
(C<sub>6</sub>H<sub>5</sub>)3PNP(C<sub>6</sub>H<sub>5</sub>)3<sup>(1+)</sup>*W(CO)3(CH<sub>3</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(CH<sub>3</sub>)2SH<sup>(1-)</sup>=(C<sub>6</sub>H<sub>5</sub>)3PNP(C<sub>6</sub>H<sub>5</sub>)3W(CO)3(CH<sub>3</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(CH<sub>3</sub>)2SH

Synonyms:(C6H5)3PNP(C6H5)3(1+)*W(CO)3(CH3)2PCH2CH2P(CH3)2SH(1-)=(C6H5)3PNP(C6H5)3W(CO)3(CH3)2PCH2CH2P(CH3)2SH

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Chemical Property of (C6H5)3PNP(C6H5)3(1+)*W(CO)3(CH3)2PCH2CH2P(CH3)2SH(1-)=(C6H5)3PNP(C6H5)3W(CO)3(CH3)2PCH2CH2P(CH3)2SH
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Technology Process of (C6H5)3PNP(C6H5)3(1+)*W(CO)3(CH3)2PCH2CH2P(CH3)2SH(1-)=(C6H5)3PNP(C6H5)3W(CO)3(CH3)2PCH2CH2P(CH3)2SH

There total 1 articles about (C6H5)3PNP(C6H5)3(1+)*W(CO)3(CH3)2PCH2CH2P(CH3)2SH(1-)=(C6H5)3PNP(C6H5)3W(CO)3(CH3)2PCH2CH2P(CH3)2SH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

[bis(triphenylphosphine)nitrogen][W(CO)5(SH)]
71771-28-3

[bis(triphenylphosphine)nitrogen][W(CO)5(SH)]

1,2-bis(dimethylphosphanyl)ethane
23936-60-9

1,2-bis(dimethylphosphanyl)ethane

fac-[bis(triphenylphosphine)nitrogen][W(CO)3(bis(dimethylphosphino)ethane)(SH)]
481657-96-9

fac-[bis(triphenylphosphine)nitrogen][W(CO)3(bis(dimethylphosphino)ethane)(SH)]

Guidance literature:
In tetrahydrofuran; under N2, mixt. was kept at 60°C for 45 min; solvent was removed, residue was washed repeatedly with Et2O and hexanes; elem. anal.;
DOI:10.1039/b203195g

Reference yield: 98.0%

(C<sub>6</sub>H<sub>5</sub>)3PNP(C<sub>6</sub>H<sub>5</sub>)3<sup>(1+)</sup>*W(CO)3(CH<sub>3</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(CH<sub>3</sub>)2SH<sup>(1-)</sup>=(C<sub>6</sub>H<sub>5</sub>)3PNP(C<sub>6</sub>H<sub>5</sub>)3W(CO)3(CH<sub>3</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(CH<sub>3</sub>)2SH
481657-96-9

(C6H5)3PNP(C6H5)3(1+)*W(CO)3(CH3)2PCH2CH2P(CH3)2SH(1-)=(C6H5)3PNP(C6H5)3W(CO)3(CH3)2PCH2CH2P(CH3)2SH

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

fac-[W(CO)3(dmpe)(η2-S=C(H)4-C6H4Cl)]
705940-64-3,706779-10-4

fac-[W(CO)3(dmpe)(η2-S=C(H)4-C6H4Cl)]

mer-[W(CO)3(dmpe)(η2-S=C(H)4-C6H4Cl)]
705940-64-3,706779-10-4

mer-[W(CO)3(dmpe)(η2-S=C(H)4-C6H4Cl)]

Guidance literature:
With trifluoroacetic acid; In tetrahydrofuran; (N2); addn. of aldehyde and CF3COOH to a soln. of tungsten complex in THF; evapn., dissolving in hexanes, column chromy. (silica gel, CH2Cl2/acetone 40:1), evapn., washing with pentane, drying in vac.; elem. anal.;
DOI:10.1016/j.ica.2003.11.032

Reference yield: 95.0%

(C<sub>6</sub>H<sub>5</sub>)3PNP(C<sub>6</sub>H<sub>5</sub>)3<sup>(1+)</sup>*W(CO)3(CH<sub>3</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(CH<sub>3</sub>)2SH<sup>(1-)</sup>=(C<sub>6</sub>H<sub>5</sub>)3PNP(C<sub>6</sub>H<sub>5</sub>)3W(CO)3(CH<sub>3</sub>)2PCH<sub>2</sub>CH<sub>2</sub>P(CH<sub>3</sub>)2SH
481657-96-9

(C6H5)3PNP(C6H5)3(1+)*W(CO)3(CH3)2PCH2CH2P(CH3)2SH(1-)=(C6H5)3PNP(C6H5)3W(CO)3(CH3)2PCH2CH2P(CH3)2SH

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

fac-[W(CO)3(dmpe)(η2-S=C(H)4-C6H4F)]
705940-59-6,706779-08-0

fac-[W(CO)3(dmpe)(η2-S=C(H)4-C6H4F)]

mer-[W(CO)3(dmpe)(η2-S=C(H)4-C6H4F)]
705940-59-6,706779-08-0

mer-[W(CO)3(dmpe)(η2-S=C(H)4-C6H4F)]

Guidance literature:
With trifluoroacetic acid; In tetrahydrofuran; (N2); addn. of aldehyde and CF3COOH to a soln. of tungsten complex in THF; evapn., dissolving in hexanes, column chromy. (silica gel, CH2Cl2/acetone 40:1), evapn., washing with pentane, drying in vac.; elem. anal.;
DOI:10.1016/j.ica.2003.11.032
upstream raw materials:

[bis(triphenylphosphine)nitrogen][W(CO)5(SH)]

1,2-bis(dimethylphosphanyl)ethane

Downstream raw materials:

fac-[W(CO)3(dmpe)(η2-S=C(H)CH=CH(4-C6H4NMe2))]

mer-[W(CO)3(dmpe)(η2-S=C(H)CH=CH(4-C6H4NMe2))]

fac-[W(CO)3(dmpe)(η2-S=C(H)C6H5)]

mer-[W(CO)3(dmpe)(η2-S=C(H)C6H5)]

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