Technology Process of dibenzyl-(2,3,4-tri-O-benzyl-6-deoxy-α-D-glucopyranosyl) phosphate
There total 10 articles about dibenzyl-(2,3,4-tri-O-benzyl-6-deoxy-α-D-glucopyranosyl) phosphate which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
N-Iodosuccinamide; trifluorormethanesulfonic acid;
In
dichloromethane;
at -30 ℃;
for 0.5h;
DOI:10.1021/ja001444y
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: 2.8 g / pyridine / 20 °C
2.1: 81.5 percent / zinc iodide / CH2Cl2 / 2 h / Heating
3.1: NaOMe / methanol; toluene / 2 h / 20 °C
4.1: NaH / dimethylformamide / 2 h / 20 °C
4.2: 480 mg / dimethylformamide
5.1: 76 percent / trifluoromethanesulfonic acid; N-iodosuccinamide / CH2Cl2 / 0.5 h / -30 °C
With
pyridine; N-Iodosuccinamide; trifluorormethanesulfonic acid; sodium methylate; sodium hydride; zinc(II) iodide;
In
methanol; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja001444y
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: 81.5 percent / zinc iodide / CH2Cl2 / 2 h / Heating
2.1: NaOMe / methanol; toluene / 2 h / 20 °C
3.1: NaH / dimethylformamide / 2 h / 20 °C
3.2: 480 mg / dimethylformamide
4.1: 76 percent / trifluoromethanesulfonic acid; N-iodosuccinamide / CH2Cl2 / 0.5 h / -30 °C
With
N-Iodosuccinamide; trifluorormethanesulfonic acid; sodium methylate; sodium hydride; zinc(II) iodide;
In
methanol; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ja001444y