(5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride

Base Information

• Chemical Name: (5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride
• CAS No.: 161407-97-2
• Molecular Formula: C₅₆H₅₂ClN₄Rh
• Molecular Weight: 919.414
• Mol file: 161407-97-2.mol

Synonyms:(5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride

Chemical Property of (5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of (5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride

There total 1 articles about (5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

rhodium(III) trichloride hydrate + 5,10,15,20-tetramesitylporphyrin → (5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride (161407-97-2)

Guidance literature:

In benzonitrile; soln. of ligand and Rh compd. in PhCN was refluxed in air for 12 h; solvent removed (vac.); chromd. (CH2Cl2); recrystd. (CH2Cl2/MeOH);

DOI:10.1021/om0604472

Reference yield: 91.0%

(5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride (161407-97-2) + benzyldimethylsilane (1631-70-5) → [Rh(5,10,15,20-tetramesitylporphyrinato)SiBnMe2] (911206-88-7)

Guidance literature:

In neat (no solvent); silane was added to Rh complex; mixt. was degassed by freeze-pump-thaw; heated at 200°C for 1 h under N2 in absence of light; chromd. (silica gel, hexane/CH2Cl2, 10/1 to 5/1); elem. anal.;

DOI:10.1021/om0604472

Reference yield: 89.0%

sodium tetrahydroborate (16940-66-2) + (5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride (161407-97-2) → (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride (124535-65-5)

Guidance literature:

sodium tetrahydroborate; (5,10,15,20-tetramesitylporphyrinato)rhodium(III) chloride; With sodium hydroxide; In ethanol; water; at 50 ℃; for 1h; Inert atmosphere;

With cyclooctyl bromide; In ethanol; water; at 20 - 30 ℃; for 0.25h; Inert atmosphere;

DOI:10.1021/acs.organomet.5b00183

Downstream raw materials:

(5,10,15,20-tetramesitylporphyrinato)bromo rhodium(III)

[Rh(5,10,15,20-tetramesitylporphyrinato)SiPhMeH]

[Rh(5,10,15,20-tetratolylporphyrinato)SiEt₃]

[Rh(5,10,15,20-tetramesitylporphyrinato)SiEt₃]