(5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride

Base Information

• Chemical Name: (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride
• CAS No.: 124535-65-5
• Molecular Formula: C₅₆H₅₃N₄Rh
• Molecular Weight: 884.969
• Mol file: 124535-65-5.mol

Synonyms:(5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride

Chemical Property of (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride

There total 18 articles about (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

sodium tetrahydroborate (16940-66-2) + (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide (85990-32-5) → (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride (124535-65-5)

Guidance literature:

In sodium hydroxide; ethanol; a soln. of NaBH4 in aq. NaOH added slowly to a suspn. of Rh complex in EtOH, heated at 55°C for 3 h; cooled to 0°C under N2, a soln. of HCl added, stirred for 15 min at 0°C, C6H6/H2O added under N2, extd. (C6H6), washed (H2O), dried (MgSO4), filtered under N2, evapd. (vac.);

DOI:10.1021/om070064j

Reference yield: 93.0%

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) (121393-39-3) → (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride (124535-65-5)

Guidance literature:

With water; triphenylphosphine; potassium hydroxide; In benzene-d6; at 120 ℃; for 48h; Inert atmosphere; Darkness;

DOI:10.1021/om200280w

Reference yield: 93.0%

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) (121393-39-3) + water (7732-18-5) → (5,10,15,20-tetramesitylporphyrinato)rhodium(III) hydride (124535-65-5)

Guidance literature:

With PPh₃; KOH; In benzene-d6; under N2; in the dark; Rh compd. reacted with H2O (50 equiv.) in presence of PPh3 (1 equiv.) and KOH (10 equiv.) in benzene-d6 at 120°C for 2 d;

DOI:10.1021/om200280w

upstream raw materials:

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

sodium tetrahydroborate

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide

(tetramesitylporphyrinato)rhodium(II)

Downstream raw materials:

5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide

ethyl (5,10,15,20-tetramesitylporphyrinato)rhodium(III) acetate

Rh(tetramesitylporphyrin)CHDCO₂Et