(E)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

Base Information

Chemical Name:(E)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide
CAS No.:1411043-26-9
Molecular Formula:C₂₅H₃₇NO₂SSi
Molecular Weight:443.726
Hs Code.:

Synonyms:(E)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

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Chemical Property of (E)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

Chemical Property:

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Technology Process of (E)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

There total 5 articles about (E)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: C₁₉H₃₂O₃SSi

: 70-55-3
toluene-4-sulfonamide

: 1411043-26-9
(E)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

: 1411043-42-9
(Z)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

Guidance literature:: toluene-4-sulfonamide; With potassium hydroxide; In N,N-dimethyl-formamide; at 120 ℃; for 0.5h; Inert atmosphere;

C₁₉H₃₂O₃SSi; In N,N-dimethyl-formamide; at 120 ℃; Overall yield = 255.2 mg; Inert atmosphere;
DOI:10.1016/j.jfluchem.2012.05.013

Reference yield:

: 1193511-16-8
(Z)-5-[diisopropyl(4-methylphenyl)silyl]pent-3-en-1-ol

: 1411043-26-9
(E)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

: 1411043-42-9
(Z)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 2 steps

1.1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere

2.1: potassium hydroxide / N,N-dimethyl-formamide / 0.5 h / 120 °C / Inert atmosphere

2.2: 120 °C / Inert atmosphere

With triethylamine; potassium hydroxide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.jfluchem.2012.05.013

Reference yield:

: 1193511-13-5
allyl(diisopropyl)(4-methylphenyl)silane

: 1411043-26-9
(E)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

: 1411043-42-9
(Z)-N-(5-(diisopropyl(p-tolyl)silyl)pent-3-en-1-yl)-4-methylbenzenesulfonamide

Guidance literature:: Multi-step reaction with 3 steps

1.1: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; p-benzoquinone / dichloromethane / Inert atmosphere

2.1: triethylamine / dichloromethane / 0 - 20 °C / Inert atmosphere

3.1: potassium hydroxide / N,N-dimethyl-formamide / 0.5 h / 120 °C / Inert atmosphere

3.2: 120 °C / Inert atmosphere

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; triethylamine; p-benzoquinone; potassium hydroxide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.jfluchem.2012.05.013