carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium

Base Information

Chemical Name:carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium
CAS No.:188970-16-3
Molecular Formula:C₆₄H₇₂N₄O₁₀RuSi₂
Molecular Weight:1214.54
Hs Code.:

carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium

Synonyms:carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium

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Chemical Property of carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium

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Technology Process of carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium

There total 1 articles about carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 188970-15-2
carbonyl[5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium

: 1066-54-2
trimethylsilylacetylene

: 188970-16-3
carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium

Guidance literature:: With triethylamine; triphenylphosphine; hexakis(acetato)tripalladium(II); In tetrahydrofuran; (argon); dissoln. of the Ru complex in THF and NEt3, addn. of the catalyst and PPh3, degassing and saturation with argon, addn. of Me3SiCCH, heating to 80°C (overnight); evapn., dissoln. (min amt. CHCl3/MeOH), chromy. (SiO2; CHCl3), recrystn.(CHCl3/MeOH);
DOI:10.1039/a605847g

Reference yield: 78.0%

: 188970-16-3
carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium

: 188970-17-4
carbonyl[5,15-bis(3-ethynylphenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; chloroform; heating the Ru complex in CHCl3 and THF under dry air to reflux, addn. of Bu4NF in THF, stirring (10 min); addn. of CaCl2 to the cooled mixture, washing (H2O), evapn., dissoln. (min. amt. CHCl3/MeOH), chromy. (SiO2; CHCl3), recrystn. (CHCl3/MeOH);
DOI:10.1039/a605847g