carbonyl[5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium

Base Information

Chemical Name:carbonyl[5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium
CAS No.:188970-15-2
Molecular Formula:C₅₄H₅₄I₂N₄O₁₀Ru
Molecular Weight:1273.92
Hs Code.:

Synonyms:carbonyl[5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium

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Chemical Property of carbonyl[5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium

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Technology Process of carbonyl[5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium

There total 1 articles about carbonyl[5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrin

: 188970-15-2
carbonyl[5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium

Guidance literature:: In decalin; (argon); 130°C (overnight); removal of decalin (vac.), filtration, washing (cold MeOH), dissoln. (min. amt. CHCl3/MeOH), chromy. (SiO2; CHCl3), collection, evapn., recrystn. (CHCl3/MeOH);
DOI:10.1039/a605847g

Reference yield: 78.0%

: 188970-15-2
carbonyl[5,15-bis(3-iodophenyl)-2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethylporphyrinato](methanol)ruthenium

: 1066-54-2
trimethylsilylacetylene

: 188970-16-3
carbonyl(methanol)[2,8,12,18-tetra(2-methoxycarbonylethyl)-3,7,13,17-tetramethyl-5,15-bis(3-(trimethylsilylethynyl)phenyl)porphyrinato]ruthenium

Guidance literature:: With triethylamine; triphenylphosphine; hexakis(acetato)tripalladium(II); In tetrahydrofuran; (argon); dissoln. of the Ru complex in THF and NEt3, addn. of the catalyst and PPh3, degassing and saturation with argon, addn. of Me3SiCCH, heating to 80°C (overnight); evapn., dissoln. (min amt. CHCl3/MeOH), chromy. (SiO2; CHCl3), recrystn.(CHCl3/MeOH);
DOI:10.1039/a605847g