buta-1,3-dien-2-yl-tributylstannane

Base Information

• Chemical Name: buta-1,3-dien-2-yl-tributylstannane
• CAS No.: 2244-38-4
• Molecular Formula: C₁₆H₃₂Sn
• Molecular Weight: 343.14
• Mol file: 2244-38-4.mol

Synonyms:buta-1,3-dien-2-yl-tributylstannane

Chemical Property of buta-1,3-dien-2-yl-tributylstannane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of buta-1,3-dien-2-yl-tributylstannane

There total 1 articles about buta-1,3-dien-2-yl-tributylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(Z)-1-Phenyl-2-tributylstannanyl-4-trimethylsilanyl-but-2-en-1-ol (112000-00-7,112000-01-8,113619-09-3) → buta-1,3-dien-2-yl-tributylstannane (2244-38-4) + trimethyl-(4-phenyl-buta-2,3-dienyl)-silane (74215-14-8)

Guidance literature:

With trifluorormethanesulfonic acid; ammonium chloride; Yield given. Multistep reaction; 1.) THF, 0 deg C, 1 min;

DOI:10.1016/S0040-4039(00)96199-9

Reference yield: 89.0%

buta-1,3-dien-2-yl-tributylstannane (2244-38-4) + benzaldehyde (100-52-7) → 2-methylene-1-phenylbut-3-en-1-ol (59163-81-4)

Guidance literature:

buta-1,3-dien-2-yl-tributylstannane; With tin(IV) chloride; In dichloromethane; N,N-dimethyl-formamide; at -78 ℃;

benzaldehyde; In dichloromethane; N,N-dimethyl-formamide; at 20 ℃; for 12h;

DOI:10.1055/s-1999-2787

Reference yield: 88.0%

3-phenyl-propionaldehyde (104-53-0) + buta-1,3-dien-2-yl-tributylstannane (2244-38-4) → 4-methylidene-1-phenylhex-5-en-3-ol (84530-96-1)

Guidance literature:

buta-1,3-dien-2-yl-tributylstannane; With tin(IV) chloride; In dichloromethane; N,N-dimethyl-formamide; at -78 ℃; for 0.916667h;

3-phenyl-propionaldehyde; In dichloromethane; N,N-dimethyl-formamide; at 20 ℃; for 12h;

DOI:10.1055/s-1999-2787

upstream raw materials:

(Z)-1-Phenyl-2-tributylstannanyl-4-trimethylsilanyl-but-2-en-1-ol

Downstream raw materials:

(E)-2-methyl-6-methylene-3,7-octadiene-2-ol

(Z)-2-methyl-6-methylene-3,7-octadiene-2-ol

2-methylene-1-phenylbut-3-en-1-ol

1-phenylpenta-4,5-dien-1-ol