ZINC(II)TETRANITROPHTHALOCYANINE

Base Information

• Chemical Name: ZINC(II)TETRANITROPHTHALOCYANINE
• CAS No.: 100043-01-4
• Molecular Formula: C₃₂H₁₂N₁₂O₈Zn
• Molecular Weight: 757.913
• Mol file: 100043-01-4.mol

Synonyms:Zinc,[2,9,16,23-tetranitro-29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32]-,(SP-4-1)-; 29H,31H-Phthalocyanine, 2,9,16,23-tetranitro-, zinc complex; Zinctetranitrophthalocyanine

Chemical Property of ZINC(II)TETRANITROPHTHALOCYANINE

Chemical Property:

• Melting Point: 239 °C (dec.)(lit.)
• PSA: 217.86000
• LogP: 6.69150

Purity/Quality:

98%,99%, ^*data from raw suppliers

Zinc(II) tetranitrophthalocyanine ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ZINC(II)TETRANITROPHTHALOCYANINE

There total 11 articles about ZINC(II)TETRANITROPHTHALOCYANINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

4-nitrophthalic anhydride (5466-84-2) + zinc diacetate (557-34-6) → zinc tetranitrophthalocyanine (100043-01-4)

Guidance literature:

With ammonium molybdate; urea; In nitrobenzene; heating of the metal acetate with 4-nitrophthalic anhydride in nitrobenzene in the presence of urea and ammonium molybdate to 180 to 190°C for 4 h; filtn., washing with hot ethanol and water, pptn. from concd. H2SO4, elem. anal.;

Reference yield: 20.26%

zinc(II) chloride hydrate + 4-nitrophthalimide (89-40-7) → zinc tetranitrophthalocyanine (100043-01-4)

Guidance literature:

With ammonium dimolybdate; ammonium chloride; urea; at 185 ℃; for 4h;

DOI:10.1149/2.0611706jes

Reference yield:

zinc(II) chloride hexahydrate + 4-nitrophthalimide (89-40-7) → zinc tetranitrophthalocyanine (100043-01-4)

Guidance literature:

With ammonium molybdate; urea; at 180 - 200 ℃; for 3h; Inert atmosphere;

DOI:10.3998/ark.5550190.p009.764

upstream raw materials:

4-nitrophthalic anhydride

zinc diacetate

tetra-4-nitrophthalocyanine

4-nitrophthalic acid

Downstream raw materials:

zinc tetraamino phthalocyanine