6-(4-tert-butylphenyl)-2,2'-bipyridine

Base Information

• Chemical Name: 6-(4-tert-butylphenyl)-2,2'-bipyridine
• CAS No.: 1160657-79-3
• Molecular Formula: C₂₀H₂₀N₂
• Molecular Weight: 288.392
• Mol file: 1160657-79-3.mol

Synonyms:6-(4-tert-butylphenyl)-2,2'-bipyridine

Chemical Property of 6-(4-tert-butylphenyl)-2,2'-bipyridine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-(4-tert-butylphenyl)-2,2'-bipyridine

There total 1 articles about 6-(4-tert-butylphenyl)-2,2'-bipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

2-bromo-6-(pyridin-2-yl)pyridine (10495-73-5) + p-tert-butylphenylboronic acid (123324-71-0) → 6-(4-tert-butylphenyl)-2,2'-bipyridine (1160657-79-3)

Guidance literature:

With tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; caesium carbonate; triphenylphosphine; cesium fluoride; In N,N-dimethyl-formamide; toluene; at 120 ℃; for 15h; Inert atmosphere;

DOI:10.1021/ja104842h

Reference yield: 80.6%

pyridine (110-86-1) + iridium(III) trichloride hydrate + 6-(4-tert-butylphenyl)-2,2'-bipyridine (1160657-79-3) → [IrCl(C5H4NC5H3NC6H3C(CH3)3)(C5H4NC5H2NC6H4C(CH3)3)] (1160657-73-7,1160928-42-6)

Guidance literature:

In 2-methoxy-ethanol; High Pressure; (Ar); heating of IrCl3*H2O (1 equiv.), 6-(4-tert-butylphenyl)-2,2'-bipyridine (2 equiv.) and 2-methoxyethanol at 130°C for 19 h in Schlenk bomb; removal of solvent under reduced pressure, passing through silica gel with CH2Cl2; as mixt. of 2 isomers; elem. anal.;

DOI:10.1021/om900014h

Reference yield:

[Ir(DMSO)3Cl] + 6-(4-tert-butylphenyl)-2,2'-bipyridine (1160657-79-3) → Ir(3+)*H(1-)*Cl(1-)*C5H4NC5H3NC6H3C(CH3)3(1-)=[IrCl(C5H4NC5H3NC6H3C(CH3)3)H]

Guidance literature:

In not given; (Ar); using Schlenk techniques; heating; monitoring by NMR;

DOI:10.1021/om900014h

upstream raw materials:

2-bromo-6-(pyridin-2-yl)pyridine

p-tert-butylphenylboronic acid

Downstream raw materials:

[IrCl(C₅H₄NC₅H₃NC₆H₃C(CH₃)3)(C₅H₄NC₅H₂NC₆H₄C(CH₃)3)]