Technology Process of Ru(salen)(triphenylphosphine)(2-(5)-imidazole-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)ClO4
There total 1 articles about Ru(salen)(triphenylphosphine)(2-(5)-imidazole-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)ClO4 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
AgBF4;
In
methanol;
byproducts: AgCl; Ru complex dissolved in CH3OH, treated with CH3OH soln. of AgBF4, refluxed for 1 h, AgCl filtered off, treated with CH3OH soln. of ligand (1 equiv.), gently refluxed for 1 h, treated with solid NaClO4; pptd. for 5 min, dissolved (CH3OH), crystd.;
DOI:10.1016/j.ica.2008.02.047
