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65849-07-2

Ru(III)(salen)(PPh3)Cl is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 65849-07-2 Structure

  • Basic information

    1. Product Name: Ru(III)(salen)(PPh3)Cl
    2. Synonyms: Ru(III)(salen)(PPh3)Cl
    3. CAS NO:65849-07-2
    4. Molecular Formula:
    5. Molecular Weight: 665.113
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 65849-07-2.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Ru(III)(salen)(PPh3)Cl(CAS DataBase Reference)
    10. NIST Chemistry Reference: Ru(III)(salen)(PPh3)Cl(65849-07-2)
    11. EPA Substance Registry System: Ru(III)(salen)(PPh3)Cl(65849-07-2)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 65849-07-2(Hazardous Substances Data)

65849-07-2 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 65849-07-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 6,5,8,4 and 9 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 65849-07:
(7*6)+(6*5)+(5*8)+(4*4)+(3*9)+(2*0)+(1*7)=162
162 % 10 = 2
So 65849-07-2 is a valid CAS Registry Number.

65849-07-2Relevant articles and documents

Synthesis, structure and catalytic alcohol oxidation by ruthenium(III) supported by Schiff base and triphenylphosphine ligands

Tang, Li-Hua,Wu, Fule,Lin, Hui,Jia, Ai-Quan,Zhang, Qian-Feng

, p. 212 - 218 (2018)

Treatment of [RuCl2(PPh3)3] with two equiv. bi-dentate Schiff base N,O-LH-Cl (N,O-LH-Cl = 2[(3-chloro-phenylimino)-methyl]-phenol) or N,O-LH-NO2 (N,O-LH-NO2 = 2[(4-nitro-phenylimino)-methyl]-phenol) in the presence of triethylamine afforded cis-[RuCl(PPh3)(κ2-N,O-L-Cl)2] (1) and trans-[RuCl(PPh3)(κ2-N,O-L-NO2)2]·Et2O (2), respectively. Reactions of [RuCl2(PPh3)3] and equal equiv. tetra-dentate Schiff bases gave corresponding ruthenium(III) complexes [RuCl(PPh3)(salen)] (3) (H2salen = N,N′-disalicylidene-1,2-ethanediamine), [RuCl(PPh3)(salipn)]·2CH2Cl2 (4) (H2salipn = N,N′-disalicylidene-1,2-(1-methyl)ethanediamine), [RuCl(PPh3)(salpn)]·CH2Cl2 (5) (H2salpn = N,N′-disalicylidene-1,2-propanediamine), [RuCl(PPh3)(salphen)]·CH2Cl2 (6) (H2salphen = N,N′-disalicylidene-1,2-phenyldiamine), [RuCl(PPh3)(saltoln)]·CH2Cl2 (7) (H2saltoln = N,N′-disalicylidene-1,2-tolyldiamine) and [RuCl(PPh3)(salcyn)] (8) (H2salcyn = N,N′-disalicylidene-(R,R)-1,2-cyclohexanediamine). The molecular structures of complexes 1–5 and 7 have been determined by single-crystal X-ray crystallography. The catalytic oxidation properties of ruthenium(III) complexes 1–8 were tested towards alcohols in the presence of N-methylmorpholine-N-oxide.

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