2,9-bis-{2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

Base Information

• Chemical Name: 2,9-bis-{2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-[1,10]phenanthroline
• CAS No.: 691413-57-7
• Molecular Formula: C₄₀H₅₂N₂O₂Si₂
• Molecular Weight: 649.036
• Mol file: 691413-57-7.mol

Synonyms:2,9-bis-{2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

Chemical Property of 2,9-bis-{2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,9-bis-{2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

There total 1 articles about 2,9-bis-{2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-[1,10]phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

2.9-dimethyl-1,10-phenanthroline (484-11-7) + (4-(bromomethyl)phenoxy) (tert-butyl) dimethylsilane (120506-39-0) → 2,9-bis-{2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-[1,10]phenanthroline (691413-57-7)

Guidance literature:

2.9-dimethyl-1,10-phenanthroline; With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 3h;

(4-(bromomethyl)phenoxy)(tert-butyl)dimethylsilane; In tetrahydrofuran; at -78 - 20 ℃; for 3h;

DOI:10.1039/b208719g

Reference yield: 97.0%

2,9-bis-{2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-[1,10]phenanthroline (691413-57-7) → C28H24N2O2 (691413-58-8)

Guidance literature:

With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃; for 3h;

DOI:10.1039/b208719g

Reference yield: 63.0%

[2-(2-(2-(allyloxy)ethoxy)ethoxy)ethyl] 4-methylbenzenesulfonate (84183-97-1) + 2,9-bis-{2-[4-(tert-butyl-dimethyl-silanyloxy)-phenyl]-ethyl}-[1,10]phenanthroline (691413-57-7) → C46H56N2O8

Guidance literature:

With cesium fluoride; In acetonitrile; at 80 ℃; for 48h; Inert atmosphere;

DOI:10.1021/jacs.7b12671

upstream raw materials:

2.9-dimethyl-1,10-phenanthroline

(4-(bromomethyl)phenoxy) (tert-butyl) dimethylsilane

Downstream raw materials:

C₂₈H₂₄N₂O₂

2,9-bis-[2-(4-benzyloxy-phenyl)-ethyl]-[1,10]phenanthroline

2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline