6,6'-bis-phenylselenyl-2,2'-bipyridine

Base Information

• Chemical Name: 6,6'-bis-phenylselenyl-2,2'-bipyridine
• CAS No.: 1206548-28-8
• Molecular Formula: C₂₂H₁₆N₂Se₂
• Molecular Weight: 466.302
• Mol file: 1206548-28-8.mol

Synonyms:6,6'-bis-phenylselenyl-2,2'-bipyridine

Chemical Property of 6,6'-bis-phenylselenyl-2,2'-bipyridine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of 6,6'-bis-phenylselenyl-2,2'-bipyridine

There total 1 articles about 6,6'-bis-phenylselenyl-2,2'-bipyridine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.1%

6,6'-Dibromo-2,2'-bipyridine (49669-22-9) + diphenyl diselenide (1666-13-3) → 6,6'-bis-phenylselenyl-2,2'-bipyridine (1206548-28-8)

Guidance literature:

With cesiumhydroxide monohydrate; In dimethyl sulfoxide; at 110 ℃; for 6h; Inert atmosphere;

DOI:10.1021/ja9047027

Reference yield: 77.4%

ruthenium trichloride hydrate (14898-67-0) + 6,6'-bis-phenylselenyl-2,2'-bipyridine (1206548-28-8) → Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl2 (1206548-32-4)

Guidance literature:

With LiCl; In ethylene glycol; stirred under Ar at 150°C for 10 h; cooled to room temp., the ppt. washed (H2O), dried under vac. overnight,dissolved in MeOH, Et2O added slowly while stirring;

DOI:10.1021/ja9047027

upstream raw materials:

6,6'-Dibromo-2,2'-bipyridine

diphenyl diselenide

Downstream raw materials:

Ru(6,6'-bis-phenylselenyl-2,2'-bipyridine)2Cl₂