2R,3S,4S,5R-hexitol hexaacetate

Base Information

• Chemical Name: 2R,3S,4S,5R-hexitol hexaacetate
• CAS No.: 75879-31-1
• Molecular Formula: C₁₈H₂₆O₁₂
• Molecular Weight: 434.397
• Mol file: 75879-31-1.mol

Synonyms:2R,3S,4S,5R-hexitol hexaacetate

Chemical Property of 2R,3S,4S,5R-hexitol hexaacetate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2R,3S,4S,5R-hexitol hexaacetate

There total 12 articles about 2R,3S,4S,5R-hexitol hexaacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

acetic anhydride (108-24-7) → hexaacetyl-D-mannitol (7208-47-1,5346-76-9) + 2R,3S,4S,5R-hexitol hexaacetate (75879-31-1,5346-76-9)

Guidance literature:

With sulfuric acid; Behandeln mit Natriummethylat-Loesung, Hydrieren an Raney-Nickel in Wasser bei 100grad und 167 at und Acetylieren;

DOI:10.1021/ja01256a053

Reference yield:

L-mannitol (643-01-6) + acetic anhydride (108-24-7) → L-mannitol hexaacetate (642-00-2,5346-77-0,7208-47-1,13443-46-4,37116-75-9,74033-72-0,75879-30-0,75879-31-1,79466-34-5,81076-18-8,82730-66-3,82730-67-4,142563-12-0,142563-13-1,142563-14-2,142563-15-3,129097-73-0,5346-76-9)

Guidance literature:

With pyridine;

Reference yield:

vinyl acetate (108-05-4,9003-20-7) + L-mannitol (643-01-6) → L-mannitol hexaacetate (642-00-2,5346-77-0,7208-47-1,13443-46-4,37116-75-9,74033-72-0,75879-30-0,75879-31-1,79466-34-5,81076-18-8,82730-66-3,82730-67-4,142563-12-0,142563-13-1,142563-14-2,142563-15-3,129097-73-0,5346-76-9)

Guidance literature:

at 20 ℃; pH=12; aq. phosphate buffer;

DOI:10.1002/rcm.6234

upstream raw materials:

L-mannitol

acetic anhydride

vinyl acetate

O¹,O²;O⁵,O⁶-Diisopropyliden-3,4-anhydro-D-talit

Downstream raw materials:

DL-iditol hexa-acetate

Refernces

• 1、 Akgul, Yurdanur,Aktas, Lale Yildiz,Anil, Huseyin. "Compounds from flowers of Daucus carota L. SSp. carota and their antioxidant activity". experimental part. p. 889 - 892. Retrieved 2010/08/06.