C₅₀H₃₁CuN₅

Base Information

• Chemical Name: C₅₀H₃₁CuN₅
• CAS No.: 1345888-86-9
• Molecular Formula: C₅₀H₃₁CuN₅
• Molecular Weight: 765.376
• Mol file: 1345888-86-9.mol

Synonyms:C₅₀H₃₁CuN₅

Chemical Property of C₅₀H₃₁CuN₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₅₀H₃₁CuN₅

There total 6 articles about C₅₀H₃₁CuN₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

C50H33N5 → C50H31CuN5 (1345888-86-9)

Guidance literature:

With copper diacetate; In toluene; for 19h; Inert atmosphere; Reflux;

DOI:10.1142/S108842461100346X

Reference yield:

(2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II) (1058186-88-1) → C50H31CuN5 (1345888-86-9)

Guidance literature:

Multi-step reaction with 3 steps

1: nitrobenzene / 19 h / Reflux

2: sulfuric acid; trifluoroacetic acid / 0.75 h

3: copper diacetate / toluene / 19 h / Inert atmosphere; Reflux

With sulfuric acid; copper diacetate; trifluoroacetic acid; In nitrobenzene; toluene;

DOI:10.1142/S108842461100346X

Reference yield:

nickel(II) 2-nitro-5,10,15,20-tetraphenylporphyrinate (95212-88-7) → C50H31CuN5 (1345888-86-9)

Guidance literature:

Multi-step reaction with 5 steps

1: hydrogenchloride; tin / chloroform; water / 20 °C

2: potassium tert-butylate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / 100 °C / Inert atmosphere

3: nitrobenzene / 19 h / Reflux

4: sulfuric acid; trifluoroacetic acid / 0.75 h

5: copper diacetate / toluene / 19 h / Inert atmosphere; Reflux

With hydrogenchloride; tin; sulfuric acid; potassium tert-butylate; copper diacetate; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; trifluoroacetic acid; In chloroform; water; nitrobenzene; toluene; 2: Buchwald-Hartwig amination;

DOI:10.1142/S108842461100346X

upstream raw materials:

(2-phenylamino-5,10,15,20-tetraphenylporphyrinato)nickel(II)

(2-amino-5,10,15,20-tetraphenylporphyrinato)-nickel(II)

nickel(II) 2-nitro-5,10,15,20-tetraphenylporphyrinate

bromobenzene