[Ru(Cp)H((R)-BINOP-F)]

Base Information

Chemical Name:[Ru(Cp)H((R)-BINOP-F)]
CAS No.:691365-08-9
Molecular Formula:C₄₉H₁₈F₂₀O₂P₂Ru
Molecular Weight:1181.67
Hs Code.:

Synonyms:[Ru(Cp)H((R)-BINOP-F)]

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Chemical Property of [Ru(Cp)H((R)-BINOP-F)]

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Technology Process of [Ru(Cp)H((R)-BINOP-F)]

There total 1 articles about [Ru(Cp)H((R)-BINOP-F)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 694494-18-3
(R)-BINOP-F

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 691365-08-9
[Ru(Cp)H((R)-BINOP-F)]

Guidance literature:: In n-heptane; using Schlenk techniques; addn. of cyclopentadiene to soln. of Ru3(CO)12in refluxing anhyd. heptane; reflux for 2 h under N2 atmosphere; coolin g to 80°C; addn. of (R)-BINOP-F; reflux for 17 h; cooling to room temp., evapn. of solvent, chromy. (aluminum oxide, neutral) with hexane and then toluene; collection of yellow band; removal of volatiles in vac.;
DOI:10.1021/ja0374123

Reference yield: 72.0%

: 75-47-8
iodoform

: 691365-08-9
[Ru(Cp)H((R)-BINOP-F)]

: 691365-06-7
[Ru(Cp)I((R)-BINOP-F)]

Guidance literature:: In acetone; using Schlenk techniques; reflux of suspn. of RuCpH(R-BINOP-F) and iodoform in acetone for 28 h; cooling to room temp.; evapn. of solvent, chromy. (silica) with mixt. ofpentane and CH2Cl2 (10:1 to 1:1); collection of orange band; removal of volatiles in vac., recrystn. from CH2Cl2/MeOH;
DOI:10.1021/ja0374123