[4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol

Base Information

Chemical Name:[4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol
CAS No.:710338-31-1
Molecular Formula:C₆₁H₇₀O₁₆
Molecular Weight:1059.22
Hs Code.:

[4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol

Synonyms:[4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol

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Chemical Property of [4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol

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Technology Process of [4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol

There total 8 articles about [4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 710338-24-2
7,12-bis[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-ol

: 710338-27-5
2-[3-allyloxy-4-(2-iodoethoxy)benzyloxy]tetrahydropyran

: 710338-31-1
[4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; at 80 ℃;
DOI:10.1039/b312979a

Reference yield:

: 756525-88-9
3-allyloxy-4-hydroxybenzyl alcohol

: 710338-31-1
[4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol

Guidance literature:: Multi-step reaction with 4 steps

1: 28 percent / K₂CO₃ / acetone / 18 h / Heating

2: 86 percent / NaI / acetone / 18 h / Heating

3: 81 percent / pyridinium para-toluenesulfonate / tetrahydrofuran; CH₂Cl₂ / 18 h / 20 °C

4: 81 percent / Cs₂CO₃ / dimethylformamide / 80 °C

With pyridinium p-toluenesulfonate; potassium carbonate; caesium carbonate; sodium iodide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1039/b312979a

Reference yield:

: 52507-49-0
4-hydroxy-3-(2-propenyloxy)benzaldehyde

: 710338-31-1
[4-(2-{7-{2-[2-allyloxy-4-(tetrahydropyran-2-yloxymethyl)phenoxy]ethoxy}-12-[2-(4-hydroxymethyl-2-methoxyphenoxy)ethoxy]-3,8,13-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononen-2-yloxy}ethoxy)-3-methoxyphenyl]methanol

Guidance literature:: Multi-step reaction with 5 steps

1: NaBH₄; NaOH / 20 °C

2: 28 percent / K₂CO₃ / acetone / 18 h / Heating

3: 86 percent / NaI / acetone / 18 h / Heating

4: 81 percent / pyridinium para-toluenesulfonate / tetrahydrofuran; CH₂Cl₂ / 18 h / 20 °C

5: 81 percent / Cs₂CO₃ / dimethylformamide / 80 °C

With sodium hydroxide; sodium tetrahydroborate; pyridinium p-toluenesulfonate; potassium carbonate; caesium carbonate; sodium iodide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.1039/b312979a