methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

Base Information

Chemical Name:methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate
CAS No.:361206-63-5
Molecular Formula:C₁₈H₂₅NO₉
Molecular Weight:399.398
Hs Code.:

Synonyms:methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

Suppliers and Price of methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

There total 6 articles about methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 98-88-4
benzoyl chloride

: 361206-58-8
methyl (methyl 9-amino-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

: 361206-63-5
methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

Guidance literature:: With triethylamine; In methanol; at -70 ℃; for 0.583333h;
DOI:10.1081/CAR-100103960

Reference yield:

: 139110-77-3
methyl 4,5,7,8,9-penta-O-acetyl-2,6-anhydro-2-chloro-2,3-dideoxy-D-glycero-D-galacto-2-nonulopyranosonate

: 361206-63-5
methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

Guidance literature:: Multi-step reaction with 5 steps

1: 6.17 g / 1 h / 20 °C

2: 59 percent / NaOMe / methanol

3: 54 percent / PPh₃; DIAD; azidotrimethylsilane / dimethylformamide / 72 h / 0 - 20 °C

4: 99 percent / H₂; AcOH / Pd/C / methanol / 84 h / 2585.74 Torr

5: 68 percent / Et₃N / methanol / 0.58 h / -70 °C

With trimethylsilylazide; di-isopropyl azodicarboxylate; hydrogen; sodium methylate; acetic acid; triethylamine; triphenylphosphine; palladium on activated charcoal; In methanol; N,N-dimethyl-formamide; 2: Zemplen de-O-acetylation;
DOI:10.1081/CAR-100103960

Reference yield:

: 142644-31-3
methyl (methyl 4,5,7,8,9-penta-O-acetyl-3-deoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

: 361206-63-5
methyl (methyl 9-benzamido-3,9-dideoxy-D-glycero-α-D-galacto-2-nonulopyranosid)onate

Guidance literature:: Multi-step reaction with 4 steps

1: 59 percent / NaOMe / methanol

2: 54 percent / PPh₃; DIAD; azidotrimethylsilane / dimethylformamide / 72 h / 0 - 20 °C

3: 99 percent / H₂; AcOH / Pd/C / methanol / 84 h / 2585.74 Torr

4: 68 percent / Et₃N / methanol / 0.58 h / -70 °C

With trimethylsilylazide; di-isopropyl azodicarboxylate; hydrogen; sodium methylate; acetic acid; triethylamine; triphenylphosphine; palladium on activated charcoal; In methanol; N,N-dimethyl-formamide; 1: Zemplen de-O-acetylation;
DOI:10.1081/CAR-100103960