7,7,7-trifluoroheptyl benzoate

Base Information

• Chemical Name: 7,7,7-trifluoroheptyl benzoate
• CAS No.: 1331743-59-9
• Molecular Formula: C₁₄H₁₇F₃O₂
• Molecular Weight: 274.283
• Mol file: 1331743-59-9.mol

Synonyms:7,7,7-trifluoroheptyl benzoate

Chemical Property of 7,7,7-trifluoroheptyl benzoate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of 7,7,7-trifluoroheptyl benzoate

There total 12 articles about 7,7,7-trifluoroheptyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

Togni's reagent II (887144-94-7) + benzoic acid hex-5-enyl ester (41795-26-0) → 7,7,7-trifluoroheptyl benzoate (1331743-59-9)

Guidance literature:

With methylene blue; 1,8-diazabicyclo[5.4.0]undec-7-ene; In N,N-dimethyl-formamide; for 3h; Schlenk technique; Inert atmosphere; Irradiation;

DOI:10.1021/cs5005823

Reference yield: 79.0%

benzoic acid hex-5-enyl ester (41795-26-0) + (trifluoromethyl)trimethylsilane (81290-20-2) → 7,7,7-trifluoroheptyl benzoate (1331743-59-9)

Guidance literature:

With [bis(acetoxy)iodo]benzene; cyclohexa-1,4-diene; sodium acetate; silver nitrate; In 1-methyl-pyrrolidin-2-one; at 20 ℃; for 10h; Inert atmosphere;

DOI:10.1002/anie.201208971

Reference yield: 78.0%

benzoic acid hex-5-enyl ester (41795-26-0) + Umemoto's reagent (129946-88-9) → 7,7,7-trifluoroheptyl benzoate (1331743-59-9)

Guidance literature:

With methanol; Ru(2,2'-bipyridine)₃Cl₂·6H₂O; at 25 ℃; for 24h; Solvent; Reagent/catalyst; regioselective reaction; Catalytic behavior; Irradiation; Inert atmosphere;

DOI:10.1021/ja401022x

upstream raw materials:

benzoic acid hex-5-enyl ester

(trifluoromethyl)trimethylsilane

iodotrifluoromethane

Umemoto's reagent