(3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl)trimethylstannane

Base Information

Chemical Name:(3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl)trimethylstannane
CAS No.:1565857-75-1
Molecular Formula:C₁₅H₂₄BBrO₂Sn
Molecular Weight:445.779
Hs Code.:

Synonyms:(3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl)trimethylstannane

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Chemical Property of (3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl)trimethylstannane

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Technology Process of (3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl)trimethylstannane

There total 4 articles about (3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl)trimethylstannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 1565857-70-6
3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

: 661-69-8
hexamethyldistannane

: 1565857-75-1
(3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl)trimethylstannane

Guidance literature:: With tert.-butylnitrite; toluene-4-sulfonic acid; In 1,2-dichloro-ethane; at 0 ℃; for 4h; Inert atmosphere;
DOI:10.1021/jo402618r

Reference yield:

: 73183-34-3
bis(pinacol)diborane

: 1565857-75-1
(3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl)trimethylstannane

Guidance literature:: Multi-step reaction with 3 steps

1: 2-(4-biphenylyl)-5-phenyloxazole; tert.-butylnitrite / acetonitrile / 4 h / 20 °C

2: 5%-palladium/activated carbon; hydrogen / methanol / 4 h / 20 °C / 760.05 Torr

3: tert.-butylnitrite; toluene-4-sulfonic acid / 1,2-dichloro-ethane / 4 h / 0 °C / Inert atmosphere

With tert.-butylnitrite; 5%-palladium/activated carbon; 2-(4-biphenylyl)-5-phenyloxazole; hydrogen; toluene-4-sulfonic acid; In methanol; 1,2-dichloro-ethane; acetonitrile;
DOI:10.1021/jo402618r

Reference yield:

: 1565857-67-1
2-(2-bromo-4-nitrophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 1565857-75-1
(3-bromo-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl)trimethylstannane

Guidance literature:: Multi-step reaction with 2 steps

1: 5%-palladium/activated carbon; hydrogen / methanol / 4 h / 20 °C / 760.05 Torr

2: tert.-butylnitrite; toluene-4-sulfonic acid / 1,2-dichloro-ethane / 4 h / 0 °C / Inert atmosphere

With tert.-butylnitrite; 5%-palladium/activated carbon; hydrogen; toluene-4-sulfonic acid; In methanol; 1,2-dichloro-ethane;
DOI:10.1021/jo402618r