C₁₃H₁₄Br₂O₃

Base Information

• Chemical Name: C₁₃H₁₄Br₂O₃
• CAS No.: 1286680-30-5
• Molecular Formula: C₁₃H₁₄Br₂O₃
• Molecular Weight: 378.06
• Mol file: 1286680-30-5.mol

Synonyms:C₁₃H₁₄Br₂O₃

Chemical Property of C₁₃H₁₄Br₂O₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

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Technology Process of C₁₃H₁₄Br₂O₃

There total 1 articles about C₁₃H₁₄Br₂O₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

C12H14O4 (1286680-17-8) + (dibromomethyl)(triphenyl)phosphonium bromide (56506-90-2) → C13H14Br2O3 (1286680-30-5)

Guidance literature:

With zinc; In 1,4-dioxane; Inert atmosphere; Reflux;

DOI:10.1002/ejoc.201001442

Reference yield: 65.0%

C13H14Br2O3 (1286680-30-5) → C13H14O3 (1286680-26-9)

Guidance literature:

With lithium diisopropyl amide; In tetrahydrofuran; at -78 ℃; for 1h;

DOI:10.1002/ejoc.201001442

Reference yield:

C13H14Br2O3 (1286680-30-5) → C26H26O6 (1286680-35-0)

Guidance literature:

Multi-step reaction with 2 steps

1: lithium diisopropyl amide / tetrahydrofuran / 1 h / -78 °C

2: copper(l) iodide / N,N-dimethyl-formamide / 40 h / 20 °C

With copper(l) iodide; lithium diisopropyl amide; In tetrahydrofuran; N,N-dimethyl-formamide;

DOI:10.1002/ejoc.201001442

upstream raw materials:

C₁₂H₁₄O₄

(dibromomethyl)(triphenyl)phosphonium bromide

Downstream raw materials:

C₁₃H₁₄O₃

C₂₆H₂₆O₆