4-nitrobenzyl trans-3-(2-tert-butyldimethylsilyloxycyclopentyl)-3-oxopropanoate

Base Information

Chemical Name:4-nitrobenzyl trans-3-(2-tert-butyldimethylsilyloxycyclopentyl)-3-oxopropanoate
CAS No.:83651-57-4
Molecular Formula:C₂₁H₃₁NO₆Si
Molecular Weight:421.566
Hs Code.:

Synonyms:4-nitrobenzyl trans-3-(2-tert-butyldimethylsilyloxycyclopentyl)-3-oxopropanoate

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Chemical Property of 4-nitrobenzyl trans-3-(2-tert-butyldimethylsilyloxycyclopentyl)-3-oxopropanoate

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Technology Process of 4-nitrobenzyl trans-3-(2-tert-butyldimethylsilyloxycyclopentyl)-3-oxopropanoate

There total 4 articles about 4-nitrobenzyl trans-3-(2-tert-butyldimethylsilyloxycyclopentyl)-3-oxopropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 83641-53-6
2,2-Dibromo-3-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-cyclopentyl]-3-oxo-propionic acid 4-nitro-benzyl ester

: 83651-57-4
4-nitrobenzyl trans-3-(2-tert-butyldimethylsilyloxycyclopentyl)-3-oxopropanoate

Guidance literature:: With sodium sulfite; In water;
DOI:10.1016/S0040-4039(00)88437-3

Reference yield:

: 3,3-Dibromo-3-[(1R,2R)-2-(tert-butyl-dimethyl-silanyloxy)-cyclopentyl]-propionic acid 4-nitro-benzyl ester

: 83651-57-4
4-nitrobenzyl trans-3-(2-tert-butyldimethylsilyloxycyclopentyl)-3-oxopropanoate

Guidance literature:: With sodium sulfite; In 1,4-dioxane; water; for 0.333333h; Yield given; Ambient temperature;
DOI:10.1248/cpb.34.1434

Reference yield:

: 83641-64-9,83680-61-9
(Z)-3-[(1S,2S)-2-(tert-Butyl-dimethyl-silanyloxy)-cyclopentyl]-3-phenylsulfanyl-acrylic acid 4-nitro-benzyl ester

: 83651-57-4
4-nitrobenzyl trans-3-(2-tert-butyldimethylsilyloxycyclopentyl)-3-oxopropanoate

Guidance literature:: Multi-step reaction with 2 steps

1: NBA / H₂O; dioxane / 0.5 h / 0 °C

2: satd. Na₂SO₃ / H₂O; dioxane / 0.33 h / Ambient temperature

With sodium sulfite; N-bromoacetamide; In 1,4-dioxane; water;
DOI:10.1248/cpb.34.1434