(E)-1-<2-(tetrahydropyranyloxy)phenyl>-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

Base Information

Chemical Name:(E)-1-<2-(tetrahydropyranyloxy)phenyl>-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene
CAS No.:77837-72-0
Molecular Formula:C₂₇H₃₆O₂
Molecular Weight:392.582
Hs Code.:

Synonyms:(E)-1-<2-(tetrahydropyranyloxy)phenyl>-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

Suppliers and Price of (E)-1-<2-(tetrahydropyranyloxy)phenyl>-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (E)-1-<2-(tetrahydropyranyloxy)phenyl>-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (E)-1-<2-(tetrahydropyranyloxy)phenyl>-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

There total 4 articles about (E)-1-<2-(tetrahydropyranyloxy)phenyl>-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 77837-70-8
methyl 2-tetrahydropyranyloxy-trans-cinnamate

: 77837-72-0,77837-73-1
2-{2-[(1Z,3E,5E)-4-Methyl-6-(2,6,6-trimethyl-cyclohex-1-enyl)-hexa-1,3,5-trienyl]-phenoxy}-tetrahydro-pyran

Guidance literature:: Multi-step reaction with 3 steps

1: DIBAL / diethyl ether; hexane / 0.5 h / 0 °C

2: MnO₂ / diethyl ether

3: NaH, Me₂SO / pentane / 1.) RT, 16 h, 2.) 60 deg C, 1 h

With manganese(IV) oxide; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; In diethyl ether; hexane; pentane;
DOI:10.1021/jm00137a019

Reference yield:

: 77837-70-8
methyl 2-tetrahydropyranyloxy-trans-cinnamate

: 77837-72-0
(E)-1-<2-(tetrahydropyranyloxy)phenyl>-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

Guidance literature:: Multi-step reaction with 3 steps

1: DIBAL / diethyl ether; hexane / 0.5 h / 0 °C

2: MnO₂ / diethyl ether

3: NaH, Me₂SO / pentane / 1.) RT, 16 h, 2.) 60 deg C, 1 h

With manganese(IV) oxide; sodium hydride; diisobutylaluminium hydride; dimethyl sulfoxide; In diethyl ether; hexane; pentane;
DOI:10.1021/jm00137a019

Reference yield:

: 66556-69-2
(E)-1-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1-buten-3-yltriphenylphosphonium bromide

: 77837-60-6
(E)-3-(2-(tetrahydropyran-2-yloxy)phenyl)acrylaldehyde

: 77837-72-0,77837-73-1
2-{2-[(1Z,3E,5E)-4-Methyl-6-(2,6,6-trimethyl-cyclohex-1-enyl)-hexa-1,3,5-trienyl]-phenoxy}-tetrahydro-pyran

: 77837-72-0
(E)-1-<2-(tetrahydropyranyloxy)phenyl>-4-methyl-6-(2,6,6-trimethyl-1-cyclohexen-1-yl)-1,3,5-hexatriene

Guidance literature:: With sodium hydride; dimethyl sulfoxide; In pentane; Yield given. Yields of byproduct given; 1.) RT, 16 h, 2.) 60 deg C, 1 h;
DOI:10.1021/jm00137a019