Sodium m-anisate

Base Information

• Chemical Name: Sodium m-anisate
• CAS No.: 17264-90-3
• Molecular Formula: C8H8 O3 . Na
• Molecular Weight: 174.132
• Hs Code.: 2918990090
• Mol file: 17264-90-3.mol

Synonyms:Benzoicacid, 3-methoxy-, sodium salt (9CI); m-Anisic acid, sodium salt (8CI); Sodium3-methoxybenzoate; Sodium m-methoxybenzoate

Chemical Property of Sodium m-anisate

Chemical Property:

• PSA: 49.36000
• LogP: 0.05870

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Sodium m-anisate

There total 2 articles about Sodium m-anisate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

3-methoxybenzyl alcohol (6971-51-3) → m-methoxybenzoic acid Na-salt (17264-90-3)

Guidance literature:

With sodium hydroxide; palladium on activated charcoal; In diethylene glycol dimethyl ether; at 160 ℃;

Reference yield:

3-methoxy-benzaldehyde (591-31-1) → m-methoxybenzoic acid Na-salt (17264-90-3)

Guidance literature:

With sodium hydroxide; sodium periodate; ruthenium trichloride; In water; at 35 ℃; Rate constant; Mechanism; other temperatures; dependence on the concentration of substrate;

Reference yield: 73.0%

m-methoxybenzoic acid Na-salt (17264-90-3) + phenylzinc iodide (23665-09-0) → 3-methoxybenzophenone (6136-67-0)

Guidance literature:

m-methoxybenzoic acid Na-salt; With chloroformic acid ethyl ester; In tetrahydrofuran; at 20 ℃; for 0.25h;

phenylzinc iodide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 70 ℃; for 14h;

DOI:10.1021/ol035801w

upstream raw materials:

3-methoxybenzyl alcohol

3-methoxy-benzaldehyde

Downstream raw materials:

1-(3-hydroxyphenyl)pentan-1-one

(3-Hydroxy-phenyl)-(3-trifluoromethyl-phenyl)-methanone

(3-Fluoro-phenyl)-(3-hydroxy-phenyl)-methanone

(3-bromophenyl)-(3-hydroxyphenyl)methanone

Refernces

• 1、 Radhakrishnamurti, P. S.,Misra, P. C.. "Kinetics and Mechanism of Ru(III)-catalysed Oxidation of Aromatic Aldehydes by Sodium Metaperiodate in Alkaline Medium: A Change in Mechanism from Hydride Loss in Acid Medium to Proton Loss in Alkaline Medium". . p. 427 - 430. Retrieved 2007/10/02.