6136-67-0

Basic information

• Product Name: 3-METHOXYBENZOPHENONE
• Synonyms: 3-METHOXYBENZOPHENONE;OTAVA-BB 1044024;UKRORGSYN-BB BBV-5118602;3-Ethoxybenzophenone;(3-Methoxyphenyl)(phenyl)Methanone
• CAS NO: 6136-67-0
• Molecular Formula: C₁₄H₁₂O₂
• Molecular Weight: 212.24
• Mol File: 6136-67-0.mol
• Article Data: 116

Chemical Properties

• Melting Point: 44°C
• Boiling Point: 343°C (estimate)
• Flash Point: 158.034 °C
• Appearance: /
• Density: 1.1035 (rough estimate)
• Vapor Pressure: 0mmHg at 25°C
• Refractive Index: 1.6000 (estimate)
• CAS DataBase Reference: 3-METHOXYBENZOPHENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-METHOXYBENZOPHENONE(6136-67-0)
• EPA Substance Registry System: 3-METHOXYBENZOPHENONE(6136-67-0)

Safety Data

• Hazardous Substances Data: 6136-67-0(Hazardous Substances Data)

Usage

Preparation

btained by photolysis of 2-bromo-3–′-methoxybenzophenone in acetonitrile under nitrogen at 350 nm for 36 min (18%).

InChI:InChI=1/C14H12O2/c1-16-13-9-5-8-12(10-13)14(15)11-6-3-2-4-7-11/h2-10H,1H3

Upstream product

• 2674-04-6 diphenyl cadmium 
• 1711-05-3 m-anisoyl chloride 
• 38111-44-3 phenylzinc(II) bromide 
• 71-43-2 benzene 
• 10365-98-7 3-methoxyphenylboronic acid 
• 98-88-4 benzoyl chloride 
• 591-50-4 iodobenzene 
• 201230-82-2 carbon monoxide 
• 95149-16-9 tris-(3-methoxy-phenyl)-bismuthane 
• 79-37-8 oxalyl dichloride 
• 603-33-8 triphenylbismuthane 
• 93-97-0 benzoic acid anhydride 
• 65-85-0 benzoic acid 
• 192569-03-2 sodium tetrakis(3-methoxyphenyl)borate 

Downstream Products

• 119870-87-0 3-methoxybenzophenone 4-methylphenylsulfonylhydrazone 
• 606100-31-6 (E)-3-(3-Methoxy-phenyl)-3-phenyl-acrylic acid ethyl ester 
• 17816-49-8 5-(3-methoxy-phenyl)-5-phenyl-imidazolidine-2,4-dione 
• 18392-21-7 5-Hydroxy-2-benzoyl-diphenylmethan 
• 18392-20-6 5-Methoxy-2-benzoyl-diphenylmethan 
• 18392-19-3 3,4-Dibenzyl-phenol Phenylurethan 
• 442190-45-6 methyl 3-(3-methoxyphenyl)-3-phenylprop-2-enoate 
• 1362100-28-4 (+/-)-(1-allyl-1H-tetrazol-5-yl)(3-methoxyphenyl)(phenyl)methanol 
• 1362100-51-3 (+/-)-(3-methoxy-phenyl)(phenyl)(1H-tetrazol-5-yl)methanol 
• 37696-01-8 1-methoxy-3-(phenylethynyl)benzene 
• 1638192-42-3 1-(2,2-difluoro-1-phenylvinyl)-3-methoxybenzene 
• 119-61-9 benzophenone 
• 13142-83-1 N-(3-methoxyphenyl)-N'-phenyl-urea 
• 13391-37-2 1-(chlorophenylmethyl)-3-methoxybenzene 

Relevant articles and documents

Geometric and solvent effects on intramolecular phenolic hydrogen abstraction by carbonyl n,π* and π,π* triplets

The photochemistry of a series of alkoxyacetophenone, -benzophenone, and -indanone derivatives, which contain a remote phenolic group linked to the ketone by a para,para′- or meta,meta′-oxyethyl spacer, has been studied in acetonitrile and dichloromethane

A Simple Synthetic Route to Well-Defined [Pd(NHC)Cl(1-tBu-indenyl)] Pre-catalysts for Cross-Coupling Reactions

The development of robust, more efficient, general, easily accessible Pd(II)–NHC pre-catalysts remains a key issue in cross-coupling applications. A selection of well-defined, air and moisture stable [Pd(NHC)Cl(1-tBu-indenyl)] (NHC=IPr, IPrCl, IMes, SIMes, IPr*) pre-catalysts have been synthesized in good to excellent yields by reacting [Pd(1-tBu-indenyl)(μ-Cl)]2 and various NHC?HCl precursors in the presence of the weak base K2CO3 in green acetone. The synthesized Pd(II)-NHC derivatives displayed excellent catalytic activity in classical Suzuki-Miyaura and Buchwald–Hartwig reactions, especially when IPrCl is employed as ancillary ligand. Additionally, in the challenging Suzuki-Miyaura reaction between esters and arylboronic acids, the [Pd(IPr*)Cl(1-tBu-indenyl)] complex exhibited the optimum catalytic activity under very mild reaction conditions.

AIBN initiated functionalization of the benzylic sp3 C[sbnd]H and C[sbnd]C bonds in the presence of dioxygen

A sp3 C[sbnd]H bond functionalization and C[sbnd]C bond cleavage were realized by AIBN/O2 catalyst system, providing a series of benzophenones under mild reaction conditions. The mechanistic study shows that a peroxide intermediate is involved in this transformation, and in the case of diphenylmethanes, the sp3 C[sbnd]C bond is cleaved through the peroxide rearrangement, which might provides a new way to cleave relatively strong C[sbnd]C bond and be applied to more general C[sbnd]C bond activation.