PHENYL CHLORODITHIOFORMATE

Base Information

• Chemical Name: PHENYL CHLORODITHIOFORMATE
• CAS No.: 16911-89-0
• Molecular Formula: C7H5 Cl S2
• Molecular Weight: 188.702
• Hs Code.: 2930909090
• Mol file: 16911-89-0.mol

Synonyms:Formicacid, chlorodithio-, phenyl ester (8CI); Phenyl chlorodithiocarbonate; Phenylchlorodithioformate; Phenyl dithiochloroformate

Chemical Property of PHENYL CHLORODITHIOFORMATE

Chemical Property:

• Vapor Pressure: 0.00964mmHg at 25°C
• Refractive Index: n20/D 1.6688(lit.)
• Boiling Point: 135 °C15 mm Hg(lit.)
• Flash Point: >230 °F
• PSA: 57.39000
• Density: 1.331 g/mL at 25 °C(lit.)
• LogP: 3.30240
• Storage Temp.: 2-8°C

Purity/Quality:

98%,99%, ^*data from raw suppliers

Phenyl Chlorodithioformate ^*data from reagent suppliers

Safty Information:

• Hazard Codes: C
• Statements: 22-34
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Phenyl chlorodithioformate was used in synthesis of phenyl arylsulfonyl-alkyl-dithiocarbamates. It was also used in synthesis of S-phenyl O-(4-nitrophenyl)dithiocarbonate.

Technology Process of PHENYL CHLORODITHIOFORMATE

There total 5 articles about PHENYL CHLORODITHIOFORMATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

thiophosgene (463-71-8) + phenylthiotrimethylsilane (4551-15-9) → phenyl chlorodithioformate (16911-89-0)

Guidance literature:

With pyridine; In diethyl ether; -5 to 0 deg C, 5 h; then 20 deg C, 3 h;

Reference yield: 53.0%

thiophosgene (463-71-8) + thiophenol (108-98-5) → phenyl chlorodithioformate (16911-89-0)

Guidance literature:

With sodium hydroxide;

DOI:10.1002/prac.19943360314

Reference yield:

CS(2+) + benzenesulfenyl chloride (931-59-9) → phenyl chlorodithioformate (16911-89-0)

Guidance literature:

In toluene; at -50 ℃;

DOI:10.1021/ja00313a058

upstream raw materials:

thiophosgene

thiophenol

phenylthiotrimethylsilane

benzenesulfenyl chloride

Downstream raw materials:

crystal violet

trithiocarbonic acid diphenyl ester

Dicyanketen-S-benzyl-S-phenylacetal

phenyl p-methoxybenzenedithiocarboxylate

Refernces

• 1、 Boberg, Friedrich,Kusserow, Joachim,Mueller, Enno,Reddig, Wolfram. "Liquid Crystalline Bisphenyl-4,4'-bibenzyldi-thiocarboxylates and -dithiocarboxylates, Syntheses and Characterization". . p. 263 - 265. Retrieved 2007/10/02.
• 2、 Mizhiritskii, M. D.,Reikhsfel'd, V. O.. "SYNTHESIS OF ORGANIC SULFUR COMPOUNDS BY MEANS OF SILICON-CONTAINING REAGENTS". . p. 1373 - 1382. Retrieved 2007/10/02.