(1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime

Base Information

Chemical Name:(1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime
CAS No.:1402140-64-0
Molecular Formula:C₂₀H₂₃NO₂Si
Molecular Weight:337.494
Hs Code.:

Synonyms:(1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime

Suppliers and Price of (1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime

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Technology Process of (1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime

There total 1 articles about (1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 21038-22-2
O-(4-methoxybenzyl)hydroxylamine

: 13829-77-1
3-(trimethylsilyl)-1-phenyl-2-propyn-1-one

: 1402140-64-0
(1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime

Guidance literature:: With pyridinium p-toluenesulfonate; In ethanol; for 12h; Reflux;
DOI:10.1021/jo301358h

Reference yield: 99.0%

: 1402140-64-0
(1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime

: 1402140-65-1
(1E)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime

Guidance literature:: With tetrabutyl ammonium fluoride; In tetrahydrofuran; at 0 ℃; for 0.5h; Inert atmosphere;
DOI:10.1021/jo301358h

Reference yield:

: 1402140-64-0
(1Z)-3-(trimethylsilyl)-1-phenyl-2-propyn-1-one O-[(4-methoxyphenyl)methyl]oxime

: 1402140-66-2
(1Z)-4-hydroxy-1-phenyl-2-butyn-1-one O-[(4-methoxyphenyl)-methyl]oxime

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere

2.1: n-butyllithium / hexane; tetrahydrofuran / 0.08 h / -40 °C / Inert atmosphere

2.2: -40 - 20 °C / Inert atmosphere

With n-butyllithium; tetrabutyl ammonium fluoride; In tetrahydrofuran; hexane;
DOI:10.1021/jo301358h