<1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene

Base Information

Chemical Name:<1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene
CAS No.:122621-69-6
Molecular Formula:C₁₃H₂₁BrO₂
Molecular Weight:289.213
Hs Code.:

Synonyms:<1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene

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Chemical Property of <1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene

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Technology Process of <1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene

There total 1 articles about <1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 473-67-6,1820-09-3,1845-30-3,5416-53-5,13040-03-4,18881-04-4,19890-02-9,22339-08-8,80795-83-1
trans-verbenol

: 67-64-1
acetone

: 122621-69-6
<1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene

Guidance literature:: With N-Bromosuccinimide; for 24h; Ambient temperature;
DOI:10.1055/s-1988-27771

Reference yield:

: 122621-69-6
<1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene

: 122620-72-8
<5R-(trans)>-1-p-Menthene-5,8-diol

Guidance literature:: Multi-step reaction with 2 steps

1: 98.7 percent / LiBHEt₃ / diethyl ether / 15 h / 23 °C

2: 100 percent / pyridinium tosylate / ethanol / 14 h / 23 °C

With pyridinium p-toluenesulfonate; lithium triethylborohydride; In diethyl ether; ethanol;
DOI:10.1002/1522-2675(200210)85:10<3400::AID-HLCA3400>3.0.CO;2-2

Reference yield:

: 122621-69-6
<1S-(1α,6β,10α)>-10-Bromo-3,3,5,5,9-pentamethyl-2,4-dioxabicyclo<4.4.0>dec-8-ene

: 122620-71-7
<5R-(trans)>-p-Mentha-1,8-dien-5-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 85 percent / LiAlH₄ / diethyl ether / 5 h / Ambient temperature

2: 49 percent / Amberlyst 15 / ethanol / 6 h / Ambient temperature

With lithium aluminium tetrahydride; Amberlyst 15; In diethyl ether; ethanol;
DOI:10.1055/s-1988-27771